Highly Chemo- and Regioselective Transfer Reduction of Aromatic Nitro Compounds using Ammonium Formate Catalyzed by Supported Gold Nanoparticles

被引：97

作者：

Lou, Xia-Bing ^{[1
]}

He, Lin ^{[1
]}

Qian, Yue ^{[1
]}

Liu, Yong-Mei ^{[1
]}

Cao, Yong ^{[1
]}

Fan, Kang-Nian ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 2-3期

基金：

中国国家自然科学基金;

关键词：

ammonium formate; chemoselectivity; gold; heterogeneous catalysis; N-formylation; nitro group reduction; ASYMMETRIC TRANSFER HYDROGENATION; CHEMOSELECTIVE REDUCTION; SELECTIVE HYDROGENATION; EFFICIENT REDUCTION; N-FORMYLATION; AMINES; ACID; CONVERSION; CHLORIDE; FACILE;

D O I：

10.1002/adsc.201000621

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A highly chemo- and regioselective reduction of a wide diversity of aromatic nitro compounds to the corresponding amines has been achieved by a combination of gold nanoparticles supported on titania and ammonium formate (HCOONH(4)) in ethanol at room temperature. Furthermore, a direct and mild route to formanilides from aromatic nitro compounds bearing different functional groups by reductive N-formylation using the gold-mediated transfer reduction protocol is also established.

引用

页码：281 / 286

页数：6

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