Monoorganotin-polyoxometal-compounds.: III.: Synthesis and crystal structure of [(nBuSn)9(VVO)3O14(OH)6Cl2(dmso)2]•3DMSO

被引：4

作者：

Izaaryene, M ^{[1
]}

Kastner, G ^{[1
]}

Reuter, H ^{[1
]}

机构：

[1] Univ Osnabruck, Inst Chem Anorg Chem 2, D-49069 Osnabruck, Germany

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 2005年 / 220卷 / 07期

关键词：

organotin compounds; vanadium; heteropolyoxometal compounds; single crystal structure analysis; X-ray diffraction;

D O I：

10.1524/zkri.220.7.622.67107

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The synthesis, molecular and crystal structure of ((BuSn)-Bu-n)(9)((VO)-O-V)(3)O-14(OH)(6)Cl-2(dmso)(2). 3 DMSO (1) are described. The yellow compound crystallizes in the monoclinic space group P2(1)/n (No. 14) with a = 17.961(5) angstrom, b 19.222(4) angstrom, c = 26.748(6) angstrom, beta = 106.776(2)degrees, V = 8842(4) angstrom(3), Z = 4. The neutral monoorganotin-polyoxovanadium molecule ((BuSn)-Bu-n)(9)((VO)-O-V)(3)O-14(OH)(6)Cl-2 x (dmso)(2) (1a) shows the same distorted icosahedral arrangement of the metal atoms and a very similar metal-oxygen framework as the well known [((PrSn)-Pr-1)(12)O-14(OH)(6)](2+) ion (2) from which it can be derived formally by substitution of three square pyramidally coordinated {RSnO4} groups by three {OVO4} groups of the same geometry. In addition, two further {RSnO4} groups are replaced by two octahedral {RSnO3Cl(dmso)} units.

引用

页码：622 / 625

页数：4

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