Monoorganotin-polyoxometal-compounds.: III.: Synthesis and crystal structure of [(nBuSn)9(VVO)3O14(OH)6Cl2(dmso)2]•3DMSO

被引：4
|
作者：
Izaaryene, M [1 ]
Kastner, G [1 ]
Reuter, H [1 ]
机构：
[1] Univ Osnabruck, Inst Chem Anorg Chem 2, D-49069 Osnabruck, Germany
来源：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 2005年 / 220卷 / 07期
关键词：
organotin compounds; vanadium; heteropolyoxometal compounds; single crystal structure analysis; X-ray diffraction;
D O I：
10.1524/zkri.220.7.622.67107
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The synthesis, molecular and crystal structure of ((BuSn)-Bu-n)(9)((VO)-O-V)(3)O-14(OH)(6)Cl-2(dmso)(2). 3 DMSO (1) are described. The yellow compound crystallizes in the monoclinic space group P2(1)/n (No. 14) with a = 17.961(5) angstrom, b 19.222(4) angstrom, c = 26.748(6) angstrom, beta = 106.776(2)degrees, V = 8842(4) angstrom(3), Z = 4. The neutral monoorganotin-polyoxovanadium molecule ((BuSn)-Bu-n)(9)((VO)-O-V)(3)O-14(OH)(6)Cl-2 x (dmso)(2) (1a) shows the same distorted icosahedral arrangement of the metal atoms and a very similar metal-oxygen framework as the well known [((PrSn)-Pr-1)(12)O-14(OH)(6)](2+) ion (2) from which it can be derived formally by substitution of three square pyramidally coordinated {RSnO4} groups by three {OVO4} groups of the same geometry. In addition, two further {RSnO4} groups are replaced by two octahedral {RSnO3Cl(dmso)} units.
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收藏
页码：622 / 625
页数：4
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