Advances of Cobalt Phthalocyanine in Electrocatalytic CO2 Reduction to CO: a Mini Review

被引:20
|
作者
Feng, Qiang [1 ]
Sun, Yuwei [1 ]
Gu, Xiang [2 ]
Dong, Zhongzhen [3 ]
机构
[1] Shandong Prov Rizhao Ecoenvironm Monitoring Ctr, Rizhao 276826, Peoples R China
[2] Hunan Univ Technol, Sch Urban & Environm, Zhuzhou 412007, Peoples R China
[3] Rizhao Ecol Environm Protect Serv Ctr, Rizhao 276826, Peoples R China
关键词
Cobalt phthalocyanine; Electrocatalysis; Carbon dioxide; Carbon monoxide; Reduction; ELECTROCHEMICAL REDUCTION; CARBON-DIOXIDE; METAL PHTHALOCYANINES; MOLECULAR CATALYSTS; ORGANIC FRAMEWORKS; COMPLEXES; CONVERSION; ELECTROREDUCTION; PORPHYRIN; EFFICIENT;
D O I
10.1007/s12678-022-00766-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electrocatalytic CO2 reduction to fuels powered by renewable electricity is a potential clean strategy to replace fossil fuels and address climate change caused by increasing CO2 emissions. In this work, the electrocatalytic CO2 reduction process was briefly introduced; the latest literature on the electrocatalytic CO2 reduction to CO by cobalt phthalocyanine (CoPc) was summarized. The structure, catalytic activity, and improvement strategies of CoPc were analyzed in detail. Then, the possible mechanism for the electrocatalytic CO2 reduction to CO was elucidated. Finally, the challenges and possible solutions of cobalt-based catalysts in electrocatalytic CO2 reduction were discussed. We believe it will serve as an up-to-date reference for the design of more efficient and stable cobalt-based catalysts for CO2 reduction, providing new insights and perspectives for further development of excellent catalytic materials.
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页码:675 / 690
页数:16
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