Synthesis of heteroleptic Cerium(IV) complexes using a heptadentate (N4O3) tripodale Schiff-base ligand

被引：33
|
作者：
Droese, Peter [1 ]
Gottfriedsen, Jochen [1 ]
机构：
[1] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 01期
关键词：
Cerium; Schiff-base ligands;
D O I：
10.1002/zaac.200700312
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Cerium(IV) complexes [{N[CH2CH2N=CH(2-O-3,5-'Bu2C6H2)(3)}CeCl] (1) and [{N[CH2CH2N=CH(2-O-3,5'Bu2C6H2)](3)}Ce(NO3)] (2) were derived from the condensation of tris(2-aminoethyl)amine and 3,5-di-tert-butylsalicylaldehyde and the appropriate Ce starting material CeCl3(H2O)(6) and (NH4)(2)[Ce(NO3)(6)], respectively. Single crystal X-ray diffraction studies reveal monomeric complexes.
引用
收藏
页码：87 / 90
页数：4
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