The effect of HIPS-g-MAH on the mechanical properties of PA66/PPO alloy

被引:13
|
作者
Zhang, Zhenya [1 ,4 ]
Cai, Kunpeng [2 ]
Liu, Shubo [1 ,3 ]
Guo, Wenhui [1 ,3 ]
Zhang, Benshang [1 ,3 ]
Yang, Mingcheng [1 ,3 ]
Liu, Wentao [2 ]
机构
[1] Henan Acad Sci Co Ltd, Inst Isotope, 7 Songshan South Rd, Zhengzhou 450015, Peoples R China
[2] Zhengzhou Univ, Sch Mat Sci & Engn, 100 Sci Ave, Zhengzhou 450001, Peoples R China
[3] Jiaozuo Tongfu Technol CO Ltd, Jiaozuo 454100, Henan, Peoples R China
[4] Korea Inst Mat Sci, Dept Extreme Environm Coatings, Chang Won 51508, Gyeongnam, South Korea
关键词
HIPS-g-MAH; PA66; PPO alloy; Mechanical properties; Coefficient of friction; Wear rate; TRIBOLOGICAL BEHAVIORS; POLY(PHENYLENE ETHER); POLYMER; PA6; GRAPHITE; BLENDS; 4-BROMO-2,6-DIMETHYLPHENOL; COMPATIBILIZATION; MORPHOLOGY;
D O I
10.1007/s00289-021-03897-2
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
HIPS-g-MAH compatibilizer and the other three compatibilizers were prepared and added to the polyamide 66/polyphenylene oxide (PA66/PPO) alloy. The FT-IR spectra showed that the maleic anhydride (MAH) had successfully undergone grafting on the high impact polystyrene (HIPS). The effect of the MAH ratio in the HIPS-g-MAH compatibilizer, the HIPS-g-MAH compatibilizer weight ratio, and the PA66/PPO ratio on the mechanical properties of PA66/PPO alloy was systematically studied. The results showed that the PA66/PPO alloy possessed the optimal mechanical properties when the HIPS-g-MAH compatibilizer weight ratio was 7% and the MAH ratio in HIPS-g-MAH compatibilizer ranged 4% similar to 8%. The fracture morphologies of PA66/PPO alloy with different HIPS-g-MAH compatibilizer weight ratios were characterized by scanning electron microscope (SEM). The PA66/PPO alloy without HIPS-g-MAH compatibilizer showed a typical brittle fracture. The mechanical properties of PA66/PPO alloys with the HIPS-g-MAH compatibilizer were improved. In addition, the crystallization temperature of PA66/PPO alloy decreased with the increase in the HIPS-g-MAH compatibilizer weight ratio. The PA66/PPO ratio also played an essential role in the PA66/PPO alloy properties. The coefficient of friction and wear rate both increased with the increase in the PPO ratio.
引用
收藏
页码:7939 / 7951
页数:13
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