Mechanism of the reaction of xenon tetraoxide with hydrogen: A photochemical reaction

被引：0

作者：

Aleinikov, NN ^{[1
]}

Vasil'ev, GK ^{[1
]}

Kashtanov, SA ^{[1
]}

Makarov, EF ^{[1
]}

Chernyshev, YA ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia

来源：

KINETICS AND CATALYSIS | 2001年 / 42卷 / 02期

关键词：

D O I：

10.1023/A:1010469418851

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dependence of the rate of a photochemical reaction of XeO4 with H-2 On the concentrations of H2 and the diluent gases He and CO2 is studied at room temperature. The results are compared with the data for the dark reaction. A mechanism with the elementary energetic branched-chain reaction OH(v) + XeO4 --> OH + O + XeO3 is proposed to explain the results of the study.

引用

页码：233 / 237

页数：5

共 50 条

[11] REACTION OF XENON DIFLUORIDE WITH HYDROGEN CHLORIDE
SHAW, MJ
HOLLOWAY, JH
HYMAN, HH
INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1970, 6 (03): : 321 - &
[12] Contributions to the Reaction Mechanism of Photochemical Decomposition of Hydrogen Peroxide in Aqueous Solution
Odochian, Lucia
Iancu, Lorela
Humelnicu, Ionel
Mocanu, Anca Mihaela
Baiceanu, Adriana
REVISTA DE CHIMIE, 2011, 62 (10): : 1012 - 1016
[13] MECHANISM OF THE PHOTOCHEMICAL HYDROGEN TRANSFER-REACTION IN DOPED FLUORENE CRYSTALS
STEHLIK, D
VIETH, HM
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1983, 93 (1-4): : 83 - 93
[14] MECHANISM OF XENON DIFLUORIDE REACTION WITH BENZENE
TURKINA, MY
GRAGEROV, IP
ZHURNAL ORGANICHESKOI KHIMII, 1975, 11 (02): : 340 - 344
[15] The photochemical hydrogen-oxygen reaction
Smith, HA
Kistiakowsky, GB
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1935, 57 (01) : 835 - 840
[16] The photochemical hydrogen-oxygen reaction
Kistiakowsky, GB
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1930, 52 : 1868 - 1874
[17] ON THE MECHANISM OF THE HYDROGEN REACTION
MAKRIDES, AC
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1962, 109 (03) : 256 - 260
[18] Probing the mechanism of the photochemical reaction of phthalaldehyde
Herling, Madison R.
Thomsen, Marcus W.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[19] THE REACTION OF MANGANESE WITH DINITROGEN TETRAOXIDE
NATSINA, AA
UKRAINTSEVA, EA
YAKOVLEV, II
IKORSKII, VN
ZHURNAL NEORGANICHESKOI KHIMII, 1981, 26 (10): : 2748 - 2752
[20] Photochemical investigations into Schumann-ultra violet Nr 6 - Mechanism of photochemical hydrogen-oxygen-reaction under consideration of thermic hydrogen-ozon-reaction
Groth, W
Harteck, P
ZEITSCHRIFT FUR ELEKTROCHEMIE UND ANGEWANDTE PHYSIKALISCHE CHEMIE, 1938, 44 : 621 - 627

← 1 2 3 4 5 →