Study of (NH4)3TiF6 electrolysis in LiF-NaF-KF melt

被引：1
|
作者：
Voroshilov, F. A. [1 ]
Luft, V. V. [1 ]
Usanova, A. S. [1 ]
机构：
[1] Natl Res Tomsk Polytech Univ, Tomsk 634050, Russia
来源：
1st International Symposium on Inorganic Fluorides: Chemistry and Technology, ISIF 2014 | 2014年 / 11卷
关键词：
electrolysis of melts; solubility; ammonium hexafluorotitanate; cathode deposit; metallic titanium; fluorides of alkali metals;
D O I：
10.1016/j.proche.2014.11.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The scope of the research is the possibility of winning titanium metal using electrolysis in molten alkali metals at the temperature of 550...700 deg. C. The resulting powder Ti composition is determined using spectral analysis methods and mass spectrometry with inductively coupled plasma. There is proven evidence that titanium metal can be recovered from ammonium fluorotitanate akin to the zirconium metal process. (C) 2014 The Authors. Published by Elsevier B.V.
引用
收藏
页码：101 / 106
页数：6
相关论文
共 50 条
  • [31] Electrochemical reduction of solutions of ReF6 in fused LiF-NaF-KF eutectic mixture
    Affoune, A.M.
    Bouteillon, J.
    Poignet, J.C.
    1600, Kluwer Academic Publishers (32):
  • [32] Density and viscosity of the (LiF-NaF-KF)eut-KBF4-B2O3 melts
    Chrenková, M
    Danek, V
    Vasiljev, R
    Silny, A
    Kremenetsky, V
    Polyakov, E
    JOURNAL OF MOLECULAR LIQUIDS, 2003, 102 (1-3) : 213 - 226
  • [33] Sorption of NdF3 and ThF4 from the LiF–NaF–KF Melt
    Yu. S. Fedorov
    V. V. Samonin
    A. S. Zotov
    E. D. Khrylova
    E. A. Spiridonova
    A. E. Miroslavov
    A. A. Akatov
    Radiochemistry, 2021, 63 : 754 - 761
  • [34] UF4, ThF4 Solubility in LiF–NaF–KF Melt
    A. A. Lizin
    S. V. Tomilin
    O. E. Gnevashov
    R. K. Gazizov
    A. G. Osipenko
    M. V. Kormilitsyn
    N. Yu. Nezgovorov
    V. S. Naumov
    L. I. Ponomarev
    Atomic Energy, 2013, 115 : 22 - 25
  • [35] An ab initio molecular dynamics study of varied compositions of the LiF-NaF-KF molten salt
    Heyl, Veronica
    Beeler, Benjamin
    JOURNAL OF NUCLEAR MATERIALS, 2023, 585
  • [36] Study on the Mechanism of Failure in the LiF-NaF-KF Molten-Salt-Purifying Processing System
    Liu, Huajian
    Chen, Shuangjian
    Fu, Jie
    Yang, Xinmei
    Tang, Rui
    Ge, Min
    Wang, Jianqiang
    Zhou, Xingtai
    Xie, Leidong
    FRONTIERS IN MATERIALS, 2022, 9
  • [37] CeF3, PuF3 Solubility in LiF–NaF–KF Melt
    M. V. Volozhin
    R. Ya. Zakirov
    P. N. Mushnikov
    V. G. Subbotin
    I. V. Sannikov
    S. P. Naumov
    Atomic Energy, 2013, 115 : 18 - 21
  • [38] Surface tension and viscosity of the molten (LiF-NaF-KF)eut-K2ZrF6 system
    Kubikova, Blanka
    Pavlik, Viliam
    Mackova, Iveta
    Boca, Miroslav
    MONATSHEFTE FUR CHEMIE, 2012, 143 (11): : 1459 - 1462
  • [39] Sorption of NdF3 and ThF4 with Activated Carbons and Zeolites from LiF-NaF-KF Molten Salts
    Fedorov, Yu S.
    Samonin, V. V.
    Zotov, A. S.
    Khrylova, E. D.
    Spiridonova, E. A.
    Miroslavov, A. E.
    Akatov, A. A.
    RADIOCHEMISTRY, 2022, 64 (03) : 308 - 314
  • [40] Phase analysis and volume properties of the (LiF-NaF-KF)eut-K2ZrF6 system
    Kubikova, B.
    Mackova, I.
    Boca, M.
    MONATSHEFTE FUR CHEMIE, 2013, 144 (03): : 295 - 300
12345