Syntheses of platinum(IV) aryl dihydride complexes via arene C-H bond activation

被引：43
|
作者：
Reinartz, S [1 ]
White, PS [1 ]
Brookhart, M [1 ]
Templeton, JL [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
来源：
ORGANOMETALLICS | 2001年 / 20卷 / 08期
关键词：
D O I：
10.1021/om001029e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tp ' PtMeH2 (1) reacts with substoichiometric amounts of B(C6F5)(3) in aromatic solvents to yield platinum(IV) aryl dihydride complexes via borane-induced reductive elimination of methane from I and subsequent C-H activation of the aromatic solvent.
引用
收藏
页码：1709 / 1712
页数：4
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