Enantioselective addition of Et2Zn to benzaldehyde activated by benzamides containing the (S)-α-phenylethyl group

被引：0

作者：

Huelgas, Gabriela ^{[1
,2
]}

Quintero, Leticia ^{[2
]}

Anaya de Parrodi, Cecilia ^{[1
]}

机构：

[1] Univ Americas Puebla, Dept Ciencias Quim Biol, Cholula 72820, Mexico

[2] Benemerita Univ Autonoma Puebla, Fac Ciencias Quim, Puebla 72570, Mexico

来源：

JOURNAL OF THE MEXICAN CHEMICAL SOCIETY | 2007年 / 51卷 / 04期

关键词：

atropisomers; benzamides; chiral ligands; diethylzinc; enantioselective addition;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Application of atropisomeric ligands, i.e. 2-aminobenzamides 1a- e and 2-sulfonamidobenzamides 2a-e, in the addition of Et2Zn to benzaldehyde afforded low to moderate enantioselectivities (up to 63% ee).

引用

页码：249 / 251

页数：3

共 33 条

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