Syntheses of K[Co(tren)(NH3)(SO4)](S4O6)•2(H2O) and of [cis-α-Co(trien)(NH3)Cl](S5O6) -: Compounds produced by hydrolytic cleavage of sulfur-sulfur bonds of the tetrathionate anion

被引：0

作者：

Chun, HP ^{[1
]}

Bernal, I ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 1999年 / 04期

关键词：

tetrathionates; pentathionates; sulfate ligands; cobalt(III) complexes; Thiobacillus ferrooxidans;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

K[Co(tren) (NH3)(SO4)](S4O6) . 2 (H2O) (1) and [cis-alpha-Co(trien)(NH3)Cl](S5O6) (2) have been prepared unexpectedly while attempting to obtain crystals suitable for X-ray diffraction of [Co(tren) (NH3)Cl](S4O6) (3) and of [cis-Co(trien)(NH3)Cl] (S4O6) (4), respectively. 1 is derived from 3 by hydrolysis of the tetrathionate anion resulting in a sulfate moiety which displaces the chloro ligand from the coordination sphere of the metal center. 2 is derived from 4 by hydrolysis of the tetrathionate anion followed by reformation into pentathionate anion and H2S, as described in previous chromatographic work by Steudel. Compounds 1 and 2 have been characterized by elemental analyses and by single-crystal X-ray diffraction studies.

引用

页码：717 / 722

页数：6

共 50 条

[31] Structure and properties of double complex salts [Co(NH3) 6][Fe(CN)6] and [Co(NH3)6] 2[Cu(C2O4)2]3
Domonov D.P.
Kuratieva N.V.
Pechenyuk S.I.
[J]. Journal of Structural Chemistry, 2011, 52 (2) : 358 - 364
[32] cis-{Pt(NH3)2(L)}2+/+ (L = Cl, H2O, NH3) binding to purines and CO:: Does π-back-donation play a role?
Baik, MH
Friesner, RA
Lippard, SJ
[J]. INORGANIC CHEMISTRY, 2003, 42 (26) : 8615 - 8617
[33] Quantum-Chemical Modeling of Anion Associates in the cis-[Co(NH3)2(C2O4)2]--S2O32- System
Gorel'skii, S. I.
Lebedev, A. Yu.
Kotov, V. Yu.
[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1998, 24 (08) : 554 - 557
[34] Cationic cobaltammines as anion receptors:: Synthesis and characterization of [Co(NH3)6](4-np)3•4H2O, [Co(NH3)6](2,4-dnp)3 and [Co(NH3)6](2,4,6-tnp)3 (where np = nitrophenolate, dnp=dinitrophenolate, tnp, trinitrophenolate), single crystal X-ray structure and packing of [Co(NH3)6](4-np)3•4H2O
Sharma, RP
Bala, R
Sharma, R
Venugopalan, P
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2005, 752 (1-3) : 170 - 177
[35] THERMAL-REACTIONS OF METAL-COMPLEXES UNDER QUASI-ISOTHERMAL AND QUASI-ISOBARIC CONDITIONS .3. SOLID-PHASE THERMAL-REACTIONS OF THE DOUBLY COMPLEXED SALTS OF THE FORMS [(CR OR CO)(NH3)6][(CR OR CO)(CN)6], [(CR OR CO)(H2O)(NH3)5][(CR OR CO)(CN)6], AND CIS-[CO(H2O)2(NH3)4][CO(CN)6]
UEHARA, A
TERABE, S
TSUCHIYA, R
[J]. INORGANIC CHEMISTRY, 1983, 22 (20) : 2864 - 2869
[36] Synthesis and structure of some Co(III)-Bi(III) heterometallic complexes:: [Co(NH3)5NCS][Bi(EDTA)]2•4H2O, trans-[Co(NH3)4(NO2)2][Bi(EDTA)(H2O)]•2H2O, and [Co(NH3)4(CO3)][Bi(EDTA)]•3H2O
Stavila, V
Wignacourt, JP
Holt, EM
Conflant, P
Drache, M
Gulea, A
[J]. INORGANICA CHIMICA ACTA, 2003, 353 : 43 - 50
[37] Controlling the aspect ratio of one-dimensional of cobalt complex ([(NH3)4Co(OH)2Co(NH3)4]Cl4(H2O)4)
Liang, Fang
Li, Linglong
Guo, Lin
Zhang, Rui
Yin, Penggang
Zhong, Qunpeng
[J]. MATERIALS CHEMISTRY AND PHYSICS, 2007, 103 (01) : 101 - 105
[38] Powder diffraction of [Co(NH3)5CO3]NO3•1/2H2O and [Co(NH3)4CO3]NO3•1/2H2O
Wu, HX
Zhu, JH
Ma, LD
Shen, XL
Shi, GS
[J]. POWDER DIFFRACTION, 1998, 13 (01) : 32 - 34
[39] REACTION OF HCRO4 WITH CO(NH3)5H2O
HAIGHT, GP
[J]. INORGANIC CHEMISTRY, 1973, 12 (06) : 1461 - 1462
[40] Quantum chemical study of the electrochemical reduction of the [Co(H2O)6]2+ and [Co(NH3)5(H2O)]2+ ions
Mendoza-Huizar, LH
Palomar-Pardavé, M
Robles, J
[J]. ELECTROCHIMICA ACTA, 2001, 46 (18) : 2749 - 2755

← 1 2 3 4 5 →