Tris(3-methyl-2,4-pentanedionato-O,O′)cobalt(III)

被引:6
|
作者
Abrahams, BF [1 ]
Hoskins, BF [1 ]
McFadyen, DW [1 ]
Perrin, LC [1 ]
机构
[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia
关键词
D O I
10.1107/S0108270198008592
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Examination of two crystalline forms of tris(methyl-acetylacetonato)cobalt(III), [Co(C6H9O2)(3)], indicate that the cobalt ion is coordinated by three chelating ligands resulting in octahedral complexes. The first crystal form is cubic with the Co atom lying on a threefold axis, and the crystal contains a small amount (similar to 1.65 molecules) of disordered water. The second crystal form is triclinic with two unique complexes.
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页码:1807 / 1809
页数:3
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