Measurements of delayed hydride cracking propagation rate in the radial direction of Zircaloy-2 cladding tubes

Delayed hydride cracking (DHC) tests of Zircaloy-2 cladding tubes were performed in the chamber of a scanning electron microscope (SEM) to directly observe the crack propagation and measure the crack velocity in the radial direction of the tubes. Pre-cracks were produced at the outer surfaces of the tubes. Hydrogen contents of the tubes were from 90 ppm to 130 ppm and test temperatures were from 225 degrees C to 300 degrees C. The crack velocity followed the Arrhenius law at temperatures lower than about 270 degrees C with apparent activation energy of about 49 kJ/mol. The upper temperature limit for DHC, above which DHC did not occur, was about 280 degrees C. The threshold stress intensity factor for the initiation of the crack propagation, K-IH was from about 4 MPa m(1/2) to 6 MPa m(1/2), almost independent of temperature. An increase in 0.2% offset yield stress of the material accelerated the crack velocity and slightly decreased K-IH. Detailed observations of crack tip movement showed that cracks propagated in an intermittent fashion and the propagation gradually approached the steady state as the crack depth increased. The SEM observations also showed that hydrides were formed at a crack tip and a number of micro-cracks were found in the hydrides. It was presumed from these observations that the repetition of precipitation and fracture of hydrides at the crack tip would be responsible for the DHC propagation. (C) 2012 Elsevier B.V. All rights reserved.