(R)-(+)-[μ-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene-κ2P: P′]bis[chlorido-gold(I)] dichloromethane solvate

被引：8
|
作者：
Bats, Jan W.
Hamzic, Melissa
Hashmi, A. Stephen K.
机构：
[1] Univ Frankfurt, Inst Organ Chem, D-60438 Frankfurt, Germany
[2] Univ Stuttgart, Inst Organ Chem, D-70569 Stuttgart, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807039529
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the crystal structure of the title compound, [Au2Cl2(C44H32P2)]center dot CH2Cl2, the molecule is located on a twofold axis. The naphthyl group is slightly bent; the angle between the planes of the two six-membered rings is 3.5 (5)degrees. The angle between the mean planes of the two symmetry-related naphthyl groups is 84.4 (1)degrees. The P-Au-Cl group is almost linear, with an angle of 175.5(1)degrees. The dichloromethane solvent molecule lies on a twofold axis and connects the AuCl groups of two symmetry-related molecules via intermolecular C-H center dot center dot center dot Cl hydrogen bonding.
引用
收藏
页码：M2344 / U899
页数：10
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