Preparation of C/SnO2 composite with rice husk-based porous carbon carrier loading ultrasmall SnO2 nanoparticles for anode in lithium-ion batteries

被引:29
|
作者
Shi, Jun [1 ]
Lin, Nan [2 ]
Liu, Debo [1 ]
Wan, Yue [1 ]
Lin, Haibo [1 ,3 ]
机构
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Energy & Proc Syst Engn, Franz Liszt Str 35, Braunschweig, Germany
[3] Jilin Univ, Zhuhai Coll, Zhuhai 519041, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
Rice husk-based porous carbon; C/SnO2; Anode; Lithium-ion batteries; ACTIVATED CARBON; NEGATIVE-ELECTRODE; MESOPOROUS CARBON; IN-SITU; PERFORMANCE; GRAPHENE; NANOCOMPOSITES; METALS; SIZE;
D O I
10.1016/j.jelechem.2019.113634
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
C/SnO2 composite with porous carbon as the carrier is usually prepared for stable SnO(2 )anodes in lithium-ion batteries. However, the application of present porous carbon materials is limited with high cost and complex preparation procedures. In our article, a C/SnO2 composite anode was fabricated using a low-cost and easily obtained rice-husk based porous carbon (RHPC). The RHPC material can be easily and cheaply obtained by convenient carbonization and activation of rice husk. Subsequently, a RHPC/SnO2 composite was prepared via a simple melt-impregnation method with heat treatment route. The HRTEM image revealed that the RHPC displayed abundant meso- and micro-pore structures. The SnO(2 )nanoparticles can be loaded on the RHPC matrix with the average size of ca. 4 nm. The cyclic measurement showed that the fifty discharge capacity of RHPC/SnO2 anodes at the current density of 100 mA g(-1) was 550 mAh g(-1) (180 mAh g(-1) for SnO2 anodes), It demonstrates that the cyclic performance of RHPC/SnO2 anodes is a remarkable enhancement by introducing the RHPC matrix in comparison with the SnO2 anodes. Moreover, the easy obtainment method of RHPC and the improved stability of SnO2 anodes promote the RHPC/SnO2 as a promising anode material in lithium-ion batteries.
引用
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页数:7
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