Effect of deuteration on the structural and magnetic properties of CuF2(H2O)2(pyrazine)

被引：5
|
作者：
Schlueter, J. A. [1 ]
Park, H. [1 ]
Manson, J. L. [2 ]
Nakotte, H. [3 ,4 ]
Schultz, A. J. [5 ]
机构：
[1] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
[2] Eastern Washington Univ, Dept Chem & Biochem, Cheney, WA 99004 USA
[3] Los Alamos Natl Lab, LANSCE, Los Alamos, NM 87545 USA
[4] New Mexico State Univ, Dept Phys, Las Cruces, NM 88003 USA
[5] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA
来源：
PHYSICA B-CONDENSED MATTER | 2010年 / 405卷 / 11期
关键词：
Isotope effect; Magnetic coordination polymer; Hydrogen bonding; Copper(II); Pyrazine; HYDROGEN; PYRAZINE;
D O I：
10.1016/j.physb.2009.11.035
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The strongest magnetic exchange interactions in the quasi-two dimensional coordination polymer CuF2(H2O)(2)(pyz) (pyz=pyrazine) lie within the CuF2(H2O)(2) plane and involve F H-O hydrogen bonds In order to better understand this novel magnetic exchange pathway the fully deuterated derivative of this complex was prepared The structural and magnetic properties of this isotopically substituted derivative are reported A slight contraction of the unit cell and reduction in the Neel temperature was observed (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码：S324 / S326
页数：3
相关论文
共 50 条
  • [21] HEI AND HEII PHOTOELECTRON-SPECTRA OF CUF AND CUF2
    LEE, EPF
    POTTS, AW
    CHEMICAL PHYSICS LETTERS, 1980, 76 (03) : 532 - 536
  • [22] Detailed ab-initio analysis of the magnetic coupling in CuF2
    Reinhardt, P
    Moreira, IDR
    de Graaf, C
    Dovesi, R
    Illas, F
    CHEMICAL PHYSICS LETTERS, 2000, 319 (5-6) : 625 - 630
  • [23] Structural and spectroscopic properties of Hexamethylenetetramine cobalt(II) complex:: [Co(NCS)2(hmt)2(H2O)2][Co(NCS)2(H2O)4] (H2O)
    Zhang, Y
    Li, J
    Xu, H
    Hou, H
    Nishiura, M
    Imamoto, T
    JOURNAL OF MOLECULAR STRUCTURE, 1999, 510 (1-3) : 191 - 196
  • [24] Effect of CuF2 on the Synthesis and Superconducting Properties of (Bi,Pb)2Sr2Ca2Cu3O10 Bulk Ceramic Samples
    J.-C. Grivel
    N. H. Andersen
    Journal of Superconductivity and Novel Magnetism, 2013, 26 : 3049 - 3056
  • [25] Importance of Halogen•••Halogen Contacts for the Structural and Magnetic Properties of CuX2(pyrazine-N,N′-dioxide)(H2O)2 (X = Cl and Br)
    Schlueter, John A.
    Park, Hyunsoo
    Halder, Gregory J.
    Armand, William R.
    Dunmars, Cortney
    Chapman, Karena W.
    Manson, Jamie L.
    Singleton, John
    McDonald, Ross
    Plonczak, Alex
    Kang, Jinhee
    Lee, Chaghoon
    Whangbo, Myung-Hwan
    Lancaster, Tom
    Steele, Andrew J.
    Franke, Isabel
    Wright, Jack D.
    Blundell, Stephen J.
    Pratt, Francis L.
    deGeorge, Joseph
    Turnbull, Mark M.
    Landee, Christopher P.
    INORGANIC CHEMISTRY, 2012, 51 (04) : 2121 - 2129
  • [26] DIELECTRIC AND STRUCTURAL PROPERTIES OF LIQUID H2O AND D2O
    YASTREMSKII, PS
    ZHURNAL STRUKTURNOI KHIMII, 1971, 12 (03): : 532 - +
  • [27] Effect of CuF2 on the Synthesis and Superconducting Properties of (Bi,Pb)2Sr2Ca2Cu3O10 Bulk Ceramic Samples
    Grivel, J-C
    Andersen, N. H.
    JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM, 2013, 26 (10) : 3049 - 3056
  • [28] Electrochemical properties of CuF2 films fabricated by pulsed laser deposition
    Zhang Hua
    Zhou Yong-Ning
    Wu Xiao-Jing
    Fu Zheng-Wen
    ACTA PHYSICO-CHIMICA SINICA, 2008, 24 (07) : 1287 - 1291
  • [29] THE HYDROGEN-BOND, AND THE STRUCTURE AND PROPERTIES OF H2O AND (H2O)2
    BUCKINGHAM, AD
    JOURNAL OF MOLECULAR STRUCTURE, 1991, 250 (2-4) : 111 - 118
  • [30] Properties of (H2O)n, (H2O)n, and (H2O)nH+ clusters.
    Jordan, KD
    Vila, F
    Christie, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U387 - U387
12345