Effect of deuteration on the structural and magnetic properties of CuF2(H2O)2(pyrazine)

被引：5
|
作者：
Schlueter, J. A. [1 ]
Park, H. [1 ]
Manson, J. L. [2 ]
Nakotte, H. [3 ,4 ]
Schultz, A. J. [5 ]
机构：
[1] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
[2] Eastern Washington Univ, Dept Chem & Biochem, Cheney, WA 99004 USA
[3] Los Alamos Natl Lab, LANSCE, Los Alamos, NM 87545 USA
[4] New Mexico State Univ, Dept Phys, Las Cruces, NM 88003 USA
[5] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA
来源：
PHYSICA B-CONDENSED MATTER | 2010年 / 405卷 / 11期
关键词：
Isotope effect; Magnetic coordination polymer; Hydrogen bonding; Copper(II); Pyrazine; HYDROGEN; PYRAZINE;
D O I：
10.1016/j.physb.2009.11.035
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The strongest magnetic exchange interactions in the quasi-two dimensional coordination polymer CuF2(H2O)(2)(pyz) (pyz=pyrazine) lie within the CuF2(H2O)(2) plane and involve F H-O hydrogen bonds In order to better understand this novel magnetic exchange pathway the fully deuterated derivative of this complex was prepared The structural and magnetic properties of this isotopically substituted derivative are reported A slight contraction of the unit cell and reduction in the Neel temperature was observed (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码：S324 / S326
页数：3
相关论文
共 50 条
  • [1] New magnetic frameworks of [(CuF2(H2O)2)x(pyz)]
    Lanza, A.
    Fiolka, C.
    Fisch, M.
    Casati, N.
    Skoulatos, M.
    Rueegg, C.
    Kraemer, K. W.
    Macchi, Piero
    CHEMICAL COMMUNICATIONS, 2014, 50 (93) : 14504 - 14507
  • [2] Magnetic properties of the S=1/2 quasisquare lattice antiferromagnet CuF2(H2O)2(pyz) (pyz = pyrazine) investigated by neutron scattering
    Wang, C. H.
    Lumsden, M. D.
    Fishman, R. S.
    Ehlers, G.
    Hong, T.
    Tian, W.
    Cao, H.
    Podlesnyak, A.
    Dunmars, C.
    Schlueter, J. A.
    Manson, J. L.
    Christianson, A. D.
    PHYSICAL REVIEW B, 2012, 86 (06):
  • [3] MAGNETIC PROPERTIES OF CUF2
    JOENK, RJ
    BOZORTH, RM
    JOURNAL OF APPLIED PHYSICS, 1965, 36 (3P2) : 1167 - &
  • [4] EPR studies of pressure induced Jahn-Teller reorientation in the coordination polymer: [CuF2(H2O)2(pyrazine)]
    Beedle, Christopher C.
    Morien, Chelsey
    Prescimone, Allessandro
    Tozer, Stan
    Manson, Jaime
    Schlueter, John
    Brechin, Euan K.
    Hill, Stephen
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [5] Pressure-Induced Magnetic Crossover Driven by Hydrogen Bonding in CuF2(H2O)2(3-chloropyridine)
    O'Neal, Kenneth R.
    Brinzari, Tatiana V.
    Wright, Joshua B.
    Ma, Chunli
    Giri, Santanab
    Schlueter, John A.
    Wang, Qian
    Jena, Puru
    Liu, Zhenxian
    Musfeldt, Janice L.
    SCIENTIFIC REPORTS, 2014, 4
  • [6] Pressure-Induced Magnetic Crossover Driven by Hydrogen Bonding in CuF2(H2O)2(3-chloropyridine)
    Kenneth R. O'Neal
    Tatiana V. Brinzari
    Joshua B. Wright
    Chunli Ma
    Santanab Giri
    John A. Schlueter
    Qian Wang
    Puru Jena
    Zhenxian Liu
    Janice L. Musfeldt
    Scientific Reports, 4
  • [7] CuF2 Structural Changes in Two-Dimensional Quantum Magnet (H2O)2(pyz) Under Pressure: Raman Study
    Olejniczak, I.
    Wolak, J.
    Barszcz, B.
    Schlueter, J. A.
    Manson, J. L.
    XXII INTERNATIONAL CONFERENCE ON RAMAN SPECTROSCOPY, 2010, 1267 : 597 - +
  • [8] Experimental and Theoretical Characterization of the Magnetic Properties of CuF2(H2O)2(pyz) (pyz = pyrazine): A Two-Dimensional Quantum Magnet Arising from Supersuperexchange Interactions through Hydrogen Bonded Paths
    Manson, Jamie L.
    Conner, Marianne M.
    Schlueter, John A.
    McConnell, Amber C.
    Southerland, Heather I.
    Malfant, Isabelle
    Lancaster, Tom
    Blundell, Stephen J.
    Brooks, Michael L.
    Pratt, Francis L.
    Singleton, John
    McDonald, Ross D.
    Lee, Changhoon
    Whangbo, Myung-Hwan
    CHEMISTRY OF MATERIALS, 2008, 20 (24) : 7408 - 7416
  • [9] Pressure-Driven Orbital Reorientations and Coordination-Sphere Reconstructions in [CuF2(H2O)2(pyz)]
    Prescimone, Alessandro
    Morien, Chelsey
    Allan, David
    Schlueter, John A.
    Tozer, Stan W.
    Manson, Jamie L.
    Parsons, Simon
    Brechin, Euan K.
    Hill, Stephen
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (30) : 7490 - 7494
  • [10] Magnetic coupling in the weak ferromagnet CuF2
    Reinhardt, P
    Habas, MP
    Dovesi, R
    Moreira, ID
    Illas, F
    PHYSICAL REVIEW B, 1999, 59 (02): : 1016 - 1023
12345