Decarbonylative C-H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A

被引：291

作者：

Amaike, Kazuma ^{[1
]}

Muto, Kei ^{[1
]}

Yamaguchi, Junichiro ^{[1
]}

Itami, Kenichiro ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 33期

关键词：

CYANOBACTERIUM NOSTOC-MUSCORUM; DIRECT ARYLATION; BOND ARYLATION; DECARBOXYLATIVE ARYLATION; BENZOIC-ACIDS; REAGENTS; FUNCTIONALIZATION; HETEROARENES; HETEROCYCLES; ANHYDRIDES;

D O I：

10.1021/ja306062c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nickel-catalyzed decarbonylative C-H biaryl coupling of azoles and aryl esters is described. The newly developed catalytic system does not require the use of expensive metal catalysts or silver- or copper-based stoichiometric oxidants. We have successfully applied this new C-H arylation reaction to a convergent formal synthesis of muscoride A.

引用

页码：13573 / 13576

页数：4

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