Solvent effect on methyl methacrylate polymerization by cerium

被引：0

作者：

Saraç, AS ^{[1
]}

Özkara, S ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2000年 / 201卷 / 18期

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Full Paper: The polymerization of methyl methacrylate (MMA) initiated by Ce-IV was conducted in DMF/Water and acetonitrile. The effect of the monomer concentration and the DMF content on the conversion were investigated. The yield of the process, which proceeds under mild conditions in the mixture of DMF and water (80/20) was high. The study was augmented by cyclic voltammetric and spectrophotometric investigation. The resulting polymer was characterized by FTIR spectroscopy, and its M-W was determined viscometrically. A possible mechanism for the polymerization is suggested. The effect of the the ratio of DMF on the conversion: [MMA] = 0.9 M, [Ce-IV] - 5 . 10(-3) M, [H2SO4] = 0.6 M, T = 25 degreesC. [GRAPHICS]

引用

页码：2742 / 2746

页数：5

共 50 条

[21] Controlled electroinduced polymerization of methyl methacrylate in the presence of catalytic amount of cerium(IV)
Saraç, AS
Özkara, S
Ustamehmetoglu, B
Sezer, E
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2003, A40 (02): : 193 - 207
[22] Poly(ethylene glycol) as a 'green solvent' for the RAFT polymerization of methyl methacrylate
West, Andrew G.
Barner-Kowollik, Christopher
Perrier, Sebastien
POLYMER, 2010, 51 (17) : 3836 - 3842
[23] POLYMERIZATION OF METHYL METHACRYLATE
DEWAR, MJS
BAMFORD, CH
NATURE, 1946, 158 (4011) : 380 - 381
[24] RADICAL POLYMERIZATION OF METHYL-METHACRYLATE IN PRESENCE OF STEREOREGULAR POLY(METHYL METHACRYLATE) .4. INFLUENCE OF SOLVENT TYPE
BUTER, R
TAN, YY
CHALLA, G
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1973, 11 (11) : 2975 - 2989
[25] SOLVENT EFFECT ON THE POLYMERIZATION OF METHYL-METHACRYLATE INITIATED BY HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)-CARBON TETRACHLORIDE
KAMEDA, N
ISHII, E
KOBUNSHI RONBUNSHU, 1979, 36 (05) : 347 - 349
[26] Polymerization of methyl methacrylate by samarium enolate - Effect of amides on polymerization behavior
Narita, M
Nomura, R
Tomita, I
Endo, T
KOBUNSHI RONBUNSHU, 2002, 59 (06) : 388 - 392
[27] Effect of titanocene dichloride on radical polymerization of methyl methacrylate
Kolesov, S.V.
Yumagulova, R.Kh.
Prokudina, E.M.
Puzin, Yu.I.
Kuznetsov, S.I.
Ionova, I.A.
Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, 2003, 45 (02): : 324 - 328
[28] Dispersion polymerization of methyl methacrylate: Effect of stabilizer concentration
Jiang, Sheng
Sudol, E. David
Dimonie, Victoria L.
El-Aasser, Mohamed S.
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (04) : 2453 - 2458
[29] EXOTHERMIC EFFECT DURING POLYMERIZATION OF POLY(METHYL METHACRYLATE
ANDREOPOULOS, AG
JOURNAL OF MATERIALS SCIENCE LETTERS, 1985, 4 (06) : 691 - 693
[30] EFFECT OF CHLOROSILANES ON RADICAL POLYMERIZATION OF STYRENE AND METHYL METHACRYLATE
MINOURA, Y
ENOMOTO, Y
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1968, 6 (1PA1): : 13 - &

← 1 2 3 4 5 →