Di-μ-chloro-bis[chloro(η5-indenyl)methyl-hafnium(IV)]

被引:1
|
作者
Morris, RJ [1 ]
Shaw, SL
Huffman, JC
Bollinger, JC
机构
[1] Ball State Univ, Dept Chem, Muncie, IN 47306 USA
[2] Indiana Univ, Dept Chem, Ctr Mol Struct, Bloomington, IN 47405 USA
关键词
D O I
10.1107/S0108270198005368
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The molecular structure of the title complex, [HfCl(mu- Cl)(CH3)(eta(5)-C9H7)](2), which is a rare example of an indenylhafnium alkyl complex, is described. In this centrosymmetric structure, the geometry around each Hf atom is best described as a pseudo-square pyramid. There is a small amount of disorder between the methyl groups and the terminal chloride ligands.
引用
收藏
页码:1617 / 1618
页数:2
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