Photochemical reflective optical fiber sensor for selective detection of phenol in aqueous solutions

被引:9
|
作者
Wang, Zhengkun [1 ]
Zhong, Nianbing [1 ]
Chen, Ming [1 ]
Chang, Haixing [2 ]
Zhong, Dengjie [2 ]
Wu, Yongwu [1 ]
Liu, Huimin [1 ]
Xin, Xin [1 ]
Zhao, Mingfu [1 ]
Tang, Bing [1 ]
Song, Tao [1 ]
Shi, Shenghui [1 ]
机构
[1] Chongqing Univ Technol, Chongqing Energy Internet Engn Ctr, Chongqing Key Lab Fiber Opt Sensor & Photodetecto, Chongqing Key Lab Modern Photoelect Detect Techno, Chongqing 400054, Peoples R China
[2] Chongqing Univ Technol, Sch Chem & Chem Engn, Chongqing 400054, Peoples R China
基金
中国国家自然科学基金;
关键词
PHOTOCATALYTIC ACTIVITY; SENSITIVITY; SURFACE; TEMPERATURE; ADSORPTION; BIOSENSOR; MEMBRANE; LACCASE; SYSTEM;
D O I
10.1364/AO.58.002091
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A photochemical fiber-optic sensor was developed by integrating a plastic optical fiber (POF), polymer membrane, gold mirror, and TiO2-based composite, and was shown to sensitively and selectively detect phenol in aqueous solution. The sensing element consisted of a thinned POF and visible-light-driven SiO2/N-doped TiO2 coating. The gold mirror was used to develop a reflective POF probe. The polymer membrane with high phenol permselectivity was employed to form a micro-channel between the membrane and probe. Our findings highlight the sensor's capability of phenol detection in aqueous solutions with high sensitivity of 0.294 x 10(-3) (mg.L-1)(-1), pH immunity ranging from 2.0 to 14.0, and high selectivity with a limit of detection of 30 mu g.L-1. (C) 2019 Optical Society of America
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页码:2091 / 2099
页数:9
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