Synthesis and characterization of highly porous borazine-linked polymers and their performance in hydrogen storage application

被引：53
|
作者：
Reich, Thomas E. [1 ]
Jackson, Karl T. [1 ]
Li, Sa [1 ]
Jena, Puru [1 ]
El-Kaderi, Hani M. [1 ]
机构：
[1] Virginia Commonwealth Univ, Dept Chem, Dept Phys, Richmond, VA 23284 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 29期
关键词：
SURFACE-AREA; INTRINSIC MICROPOROSITY; RETICULAR SYNTHESIS; CRYSTALLINE; FRAMEWORK; NETWORKS;
D O I：
10.1039/c1jm11455g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new class of highly porous borazine-linked polymers (BLPs) has been synthesized utilizing arylamines and boron trihalides. BLPs exhibit Brunauer-Emmett-Teller (BET) surface areas in the range of 503 to 1364 m(2) g(-1) and store up to 1.3 wt% of hydrogen with 7.1 kJ mol(-1) isosteric heat of adsorption.
引用
收藏
页码：10629 / 10632
页数：4
相关论文
共 50 条
  • [31] Synthesis, characterization, and hydrogen storage capacities of hierarchical porous carbide derived carbon monolith
    Wang, Jiacheng
    Oschatz, Martin
    Biemelt, Tim
    Borchardt, Lars
    Senkovska, Irena
    Lohe, Martin R.
    Kaskel, Stefan
    JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (45) : 23893 - 23899
  • [32] Synthesis and characterization of porous HKUST-1 metal organic frameworks for hydrogen storage
    Lin, Kuen-Song
    Adhikari, Abhijit Krishna
    Ku, Chi-Nan
    Chiang, Chao-Lung
    Kuo, Hua
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (18) : 13865 - 13871
  • [33] Synthesis and characterization of porous polyaniline conductive polymers
    Price, Aaron D.
    Naguib, Hani E.
    ELECTROACTIVE POLYMER ACTUATORS AND DEVICES (EAPAD) 2007, 2007, 6524
  • [34] Synthesis and characterization of porous polyaniline conductive polymers
    Price, Aaron D.
    Naguib, Hani E.
    CELLULAR POLYMERS, 2008, 27 (03) : 201 - 212
  • [35] Radical polymerization synthesis and characterization of porous polymers
    Reinhold, Gunter
    Trimmer, Clara T.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [36] Synthesis and characterization of conjugated porous polyazomethines with excellent electrochemical energy storage performance
    P. H. Salunkhe
    Y. S. Patil
    V. B. Patil
    Y. H. Navale
    I. A. Dhole
    V. P. Ubale
    N. N. Maldar
    A. A. Ghanwat
    Journal of Polymer Research, 2018, 25
  • [37] Synthesis and characterization of conjugated porous polyazomethines with excellent electrochemical energy storage performance
    Salunkhe, P. H.
    Patil, Y. S.
    Patil, V. B.
    Navale, Y. H.
    Dhole, I. A.
    Ubale, V. P.
    Maldar, N. N.
    Ghanwat, A. A.
    JOURNAL OF POLYMER RESEARCH, 2018, 25 (07)
  • [38] Highly efficient catalytic derived synthesis process of carbon aerogel for hydrogen storage application
    Pandey, Anant Prakash
    Shaz, M. A.
    Sekkar, V.
    Tiwari, R. S.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (56) : 21404 - 21411
  • [39] Synthesis and Characterization of Hydrazide-Linked and Amide Linked Organic Polymers
    Liu, Zhongshan
    Ou, Junjie
    Wang, Hongwei
    You, Xin
    Ye, Mingliang
    ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (46) : 32060 - 32067
  • [40] Synthesis, characterization, and application of helical polymers
    Okamoto, Y
    MACROMOLECULAR SYMPOSIA, 1996, 101 : 343 - 354
12345