Synthesis and characterization of highly porous borazine-linked polymers and their performance in hydrogen storage application

被引：53
|
作者：
Reich, Thomas E. [1 ]
Jackson, Karl T. [1 ]
Li, Sa [1 ]
Jena, Puru [1 ]
El-Kaderi, Hani M. [1 ]
机构：
[1] Virginia Commonwealth Univ, Dept Chem, Dept Phys, Richmond, VA 23284 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 29期
关键词：
SURFACE-AREA; INTRINSIC MICROPOROSITY; RETICULAR SYNTHESIS; CRYSTALLINE; FRAMEWORK; NETWORKS;
D O I：
10.1039/c1jm11455g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new class of highly porous borazine-linked polymers (BLPs) has been synthesized utilizing arylamines and boron trihalides. BLPs exhibit Brunauer-Emmett-Teller (BET) surface areas in the range of 503 to 1364 m(2) g(-1) and store up to 1.3 wt% of hydrogen with 7.1 kJ mol(-1) isosteric heat of adsorption.
引用
收藏
页码：10629 / 10632
页数：4
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