Reaction of methanol and n-propanol over hydrotalcite-like catalysts containing vanadium oxide

被引：10

作者：

Dinka, P ^{[1
]}

Prandová, K ^{[1
]}

Hronec, M ^{[1
]}

机构：

[1] Slovak Univ Technol Bratislava, Dept Organ Technol, Bratislava 81237, Slovakia

来源：

APPLIED CLAY SCIENCE | 1998年 / 13卷 / 5-6期

关键词：

hydrotalcite; hydrotalcite-like compounds; polyoxovanadate pillared hydrotalcite; isobutyric aldehyde;

D O I：

10.1016/S0169-1317(98)00039-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vapour phase synthesis of isobutyric aldehyde from methanol and n-propanol (molar ratio 10:1) was carried out in a fixed bed reactor over calcined hydrotalcites and hydrotalcite-like compounds containing various amounts of vanadium oxide. V2O5 was loaded by impregnation or by decomposition of intercalated decavanadate ions. The influence of the Mg/Al ratio, and the V2O5 content as well as effect of some other reaction parameters was studied for both types of catalysts. The mechanism of isobutyric aldehyde formation from n-propyl alcohol and methanol involves formation of metal enolates as intermediates. The catalysts were characterized by X-ray diffraction (XRD), temperature-programmed reduction (TPR), surface area and basicity measurements. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：467 / 477

页数：11

共 50 条

[41] Selective Ortho alkylation of phenol with alcohols over catalysts derived from hydrotalcite-like anionic clays
S. Velu
C. S. Swamy
Research on Chemical Intermediates, 2000, 26 : 295 - 302
[42] Dehydrogenation of ethylbenzene to styrene in the presence of CO2 over calcined hydrotalcite-like compounds as catalysts
Mimura, N
Takahara, I
Saito, M
Sasaki, Y
Murata, K
CATALYSIS LETTERS, 2002, 78 (1-4) : 125 - 128
[43] Steam reforming of sunflower oil over Ni/Al catalysts prepared from hydrotalcite-like materials
Marquevich, M
Farriol, X
Medina, F
Montané, D
CATALYSIS LETTERS, 2003, 85 (1-2) : 41 - 48
[44] Thermally activated hydrotalcite-like materials as catalysts of nitrogen monoxide (N2O) decomposition
Kustrowski, P
Chmielarz, L
Rafalska-Lasocha, A
Dudek, B
Wegrzyn, A
Dziembaj, R
PRZEMYSL CHEMICZNY, 2003, 82 (8-9): : 732 - 735
[45] Hydrotalcite-like compounds derived highly effective Cu-based catalysts for CO2 hydrogenation to methanol
Gao, Peng
Wang, Hui
Xiao, Shuo
Zhang, Yanfei
Wei, Wei
Sun, Yuhan
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
[46] Highly efficient Cu-based catalysts via hydrotalcite-like precursors for CO2 hydrogenation to methanol
Xiao, Shuo
Zhang, Yanfei
Gao, Peng
Zhong, Liangshu
Li, Xiaopeng
Zhang, Zhongzheng
Wang, Hui
Wei, Wei
Sun, Yuhan
CATALYSIS TODAY, 2017, 281 : 327 - 336
[47] The oxidative dehydrogenation of n-octane to styrene using catalysts derived from hydrotalcite-like precursors
Friedrich, Holger B.
Mahomed, Abdul S.
APPLIED CATALYSIS A-GENERAL, 2008, 347 (01) : 11 - 22
[48] Selective synthesis of isobutanol by means of the Guerbet reaction Part 2.: Reaction of methanol/ethanol and methanol/ethanol/n-propanol mixtures over copper based/MeONa catalytic systems
Carlini, C
Di Girolamo, M
Macinai, A
Marchionna, M
Noviello, M
Galletti, AMR
Sbrana, G
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 200 (1-2) : 137 - 146
[49] The Study on Higher Alcohols Synthesis from Syngas over CuZnAl Catalysts Derived from Hydrotalcite-Like Precursors
Zhang, Sai
Gao, Zhihua
Liu, Yan
Bai, Nan
Huang, Wei
CHEMISTRYSELECT, 2020, 5 (28): : 8696 - 8700
[50] Hydrodeoxygenation of furfuryl alcohol over Cu/MgAl and Cu/ZnAl catalysts derived from hydrotalcite-like precursors
Pino, N.
Hincapie, G.
Lopez, D.
INGENIERIA E INVESTIGACION, 2017, 37 (01): : 34 - 42

← 1 2 3 4 5 →