New chlorinated peptides from the tropical marine sponge Dysidea sp.

被引：22
|
作者：
Stapleton, BL [1 ]
Cameron, GM [1 ]
Garson, MJ [1 ]
机构：
[1] Univ Queensland, Dept Chem, Brisbane, Qld 4072, Australia
来源：
TETRAHEDRON | 2001年 / 57卷 / 21期
基金：
澳大利亚研究理事会;
关键词：
chlorinated peptide; DIBAH; NaBH4; NMR; sponges;
D O I：
10.1016/S0040-4020(01)00379-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Five new chlorinated peptides (5)-(9) have been isolated from a Dysidea sp. and identified by two-dimensional NMR spectroscopy. The absolute stereochemistry of the metabolites was deduced by chemical correlation with S-(-)-4,4,4-trichloro-3-methylbutanoic acid (10) and with an alcohol (11). (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4603 / 4607
页数：5
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