The formation of photodegradable nitrophenylene polymers via ring-opening metathesis polymerization

被引：8
|
作者：
Koo, Bonwoo [1 ]
Kim, Dopil [1 ]
Song, Da Yong [1 ]
Han, Woo Joo [1 ]
Kim, Dongwook [2 ]
Park, Jae Woo [1 ]
Kim, Min [1 ]
Kim, Cheoljae [1 ]
机构：
[1] Chungbuk Natl Univ, Dept Chem, Cheongju 28644, South Korea
[2] Inst Basic Sci IBS, Ctr Catalyt Hydrocarbon Functionalizat, Daejeon 34141, South Korea
来源：
POLYMER CHEMISTRY | 2022年 / 13卷 / 45期
基金：
新加坡国家研究基金会;
关键词：
ROMP;
D O I：
10.1039/d2py00684g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A photodegradable nitrophenylene polymer was prepared via ring-opening metathesis polymerization (ROMP). Newly designed macrocyclic monomers bearing an ortho-nitrobenzyl ester were successfully polymerized by using a Grubbs-type catalyst within 30 minutes. The DFT calculated Gibbs free energies of ring-opening reactions support polymerization reactivities from macrocyclic monomers with low ring strain. The resulting polymers were cleaved in the presence of UVA light without any chemical additives within 1 hour.
引用
收藏
页码：6268 / 6273
页数：7
相关论文
共 50 条
  • [21] Polymers with novel topologies by ring-opening metathesis polymerization of macromonomers
    Grande, D
    Six, JL
    Breunig, S
    Heroguez, V
    Fontanille, M
    Gnanou, Y
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 1998, 9 (10-11) : 601 - 612
  • [22] Porous polymers via ring opening metathesis polymerization
    He, Yuan
    Zhao, Yanchuan
    Swager, Timothy
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [23] Synthesis of two zwitterionic polymers produced via ring-opening metathesis polymerization.
    Vlaminck, JJ
    Ippoliti, JT
    Hillmyer, MA
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U541 - U541
  • [24] AMINO-ACID DERIVED HOMOCHIRAL POLYMERS VIA RING-OPENING METATHESIS POLYMERIZATION
    COLES, MP
    GIBSON, VC
    MAZZARIOL, L
    NORTH, M
    TEASDALE, WG
    WILLIAMS, CM
    ZAMUNER, D
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (21) : 2505 - 2506
  • [25] Bottlebrush polymers via ring-opening metathesis polymerization (ROMP): Synthesis, properties and applications
    Rekha Rout, Smruti
    Kenguva, Gowtham
    Mansuri, Shaaba
    Manu, K.R.
    Dandela, Rambabu
    Pramanik, Nabendu B.
    [J]. European Polymer Journal, 221
  • [26] Trends in ring-opening metathesis polymerization
    Stelzer, F
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1996, A33 (07): : 941 - 952
  • [27] RING-OPENING METATHESIS POLYMERIZATION CATALYSTS
    GRUBBS, RH
    JOHNSON, LK
    NOVAK, BM
    HILLMYER, M
    BENEDICTO, A
    FRANCE, M
    NGUYEN, ST
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 456 - POLY
  • [28] Living ring-opening metathesis polymerization
    Bielawski, Christopher W.
    Grubbs, Robert H.
    [J]. PROGRESS IN POLYMER SCIENCE, 2007, 32 (01) : 1 - 29
  • [29] Carbodiimide Ring-Opening Metathesis Polymerization
    Johnson, J. Drake
    Kaplan, Samuel W.
    Toth, Jozsef
    Wang, Zian
    Maw, Mitchell
    Sheiko, Sergei S.
    Zhukhovitskiy, Aleksandr V.
    [J]. ACS CENTRAL SCIENCE, 2023, 9 (06) : 1104 - 1110
  • [30] Ring-Opening Metathesis Polymerization of Thianorbornenes
    Cho, Youngsang
    Kim, Yeram
    Seo, Jinwon
    Bielawski, Christopher W.
    [J]. ACS Macro Letters, 2024, 13 (11) : 1509 - 1514
12345