The formation of photodegradable nitrophenylene polymers via ring-opening metathesis polymerization

被引：8
|
作者：
Koo, Bonwoo [1 ]
Kim, Dopil [1 ]
Song, Da Yong [1 ]
Han, Woo Joo [1 ]
Kim, Dongwook [2 ]
Park, Jae Woo [1 ]
Kim, Min [1 ]
Kim, Cheoljae [1 ]
机构：
[1] Chungbuk Natl Univ, Dept Chem, Cheongju 28644, South Korea
[2] Inst Basic Sci IBS, Ctr Catalyt Hydrocarbon Functionalizat, Daejeon 34141, South Korea
来源：
POLYMER CHEMISTRY | 2022年 / 13卷 / 45期
基金：
新加坡国家研究基金会;
关键词：
ROMP;
D O I：
10.1039/d2py00684g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A photodegradable nitrophenylene polymer was prepared via ring-opening metathesis polymerization (ROMP). Newly designed macrocyclic monomers bearing an ortho-nitrobenzyl ester were successfully polymerized by using a Grubbs-type catalyst within 30 minutes. The DFT calculated Gibbs free energies of ring-opening reactions support polymerization reactivities from macrocyclic monomers with low ring strain. The resulting polymers were cleaved in the presence of UVA light without any chemical additives within 1 hour.
引用
收藏
页码：6268 / 6273
页数：7
相关论文
共 50 条
  • [1] Backbone-Photodegradable Polymers by Incorporating Acylsilane Monomers via Ring-Opening Metathesis Polymerization
    Huang, Banruo
    Wei, Mufeng
    Vargo, Emma
    Qian, Yiwen
    Xu, Ting
    Toste, F. Dean
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (43) : 17920 - 17925
  • [2] Metallosupramolecular polymers via ring-opening metathesis polymerization
    Elacqua, Elizabeth
    Weck, Marcus
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [3] Synthesis of dendronized polymers via ring-opening metathesis polymerization
    Jung, Hwayoon
    Week, Marcus
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [4] HYDROGENATION OF RING-OPENING METATHESIS POLYMERIZATION POLYMERS
    SOHN, BH
    GRATT, JA
    LEE, IK
    COHEN, RE
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 58 (06) : 1041 - 1046
  • [5] Synthesis of Polyisobutylene Bottlebrush Polymers via Ring-Opening Metathesis Polymerization
    Yang, Bin
    Abel, Brooks A.
    McCormick, Charles L.
    Storey, Robson F.
    [J]. MACROMOLECULES, 2017, 50 (19) : 7458 - 7467
  • [6] Vanillin-Based Polymers via Ring-Opening Metathesis Polymerization
    Koo, Byungjin
    [J]. ACS APPLIED POLYMER MATERIALS, 2024, 6 (03): : 1653 - 1661
  • [7] Thermoresponsive polymers based on ring-opening metathesis polymerization
    Zhao, Yuming
    Zhang, Ke
    [J]. POLYMER CHEMISTRY, 2016, 7 (24) : 4081 - 4089
  • [8] Synthesis of Bottlebrush Polymers by Ring-Opening Metathesis Polymerization
    Chen, Kerui
    Hu, Xin
    Qiu, Jiangkai
    Zhu, Ning
    Guo, Kai
    [J]. PROGRESS IN CHEMISTRY, 2020, 32 (01) : 93 - 102
  • [9] Photoresponsive Polymers Containing Nitrobenzyl Esters via Ring-Opening Metathesis Polymerization
    Gumbley, Patricia
    Koylu, Damla
    Thomas, Samuel W., III
    [J]. MACROMOLECULES, 2011, 44 (20) : 7956 - 7961
  • [10] Strained alkyne polymers capable of SPAAC via ring-opening metathesis polymerization
    Vasdev, Rajeshwar
    Luo, Wilson
    Classen, Kyle
    Anghel, Michael
    Novoa, Samantha
    Workentin, Mark S.
    Gilroy, Joe B.
    [J]. POLYMER CHEMISTRY, 2021, 12 (38) : 5542 - 5547
12345