Copper-catalyzed protodecarboxylation of aromatic carboxylic acids

被引：177
|
作者：
Goossen, Lukas J. [1 ]
Thiel, Werner R. [1 ]
Rodriguez, Nuria [1 ]
Linder, Christophe [1 ]
Melzer, Bettina [1 ]
机构：
[1] Tech Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 14-15期
关键词：
arenes; carboxylic acids; catalysis; copper; decarboxylation; DECARBOXYLATION; MECHANISMS; INITIO;
D O I：
10.1002/adsc.200700223
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A catalyst generated from copper(I) oxide and 4,7-diphenyl-1,10-phenanthroline for the first time allows the catalytic protodecarboxylation even of deactivated aromatic carboxylic acids, giving rise to the corresponding arenes. Based on DFT calculations, a reaction pathway is proposed that accurately reflects the experimental results, such as the observed reactivity order of the substrates.
引用
收藏
页码：2241 / 2246
页数：6
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