Saturated-liquid viscosity of ten binary and ternary alternative refrigerant mixtures. Part I: Measurements

被引:19
|
作者
Laesecke, A [1 ]
Hafer, RF [1 ]
Morris, DJ [1 ]
机构
[1] Natl Inst Stand & Technol, Phys & Chem Properties Div, Expt Properties Fluids Grp, Boulder, CO 80305 USA
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D O I
10.1021/je000335w
中图分类号
O414.1 [热力学];
学科分类号
摘要
The saturated-liquid viscosities of 10 binary and ternary refrigerant mixtures composed of difluoromethane (R32), 1,1,1,2-tetrafluoroethane (R134a), pentafluoroethane (R125), and propane (R290) were measured in a sealed gravitational capillary viscometer with a straight vertical capillary from 245 to 345 K or to a maximum vapor pressure of 3 MPa. The maximum uncertainty of the measurements is estimated to be +/-2.8% for the mixtures of R32 + propane. The largest contribution to the total uncertainty is that of the saturated liquid and vapor densities of the mixtures, which had to be estimated. Comparisons with; viscosity data from the literature show agreement within the mutual uncertainty for all but one data set. Similar. agreement is found with predicted viscosities using the extended-corresponding-states model in NIST Standard Reference Database 23(REFPROP), except for the mixtures of the polar fluids R32 rand R134-a with the nonpolar propane. Their viscosity-composition dependences are strongly nonlinear.
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页码:433 / 445
页数:13
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