Effect of acidification on spectral parameters of solutions of mixed-ligand cyclometalated Pt(II) and Pd(II) complexes

被引：2
|
作者：
Puzyk, MV [1 ]
Ivanov, YA [1 ]
Balashev, KP [1 ]
机构：
[1] Herzen State Pedag Univ, St Petersburg 191186, Russia
来源：
OPTICS AND SPECTROSCOPY | 2003年 / 95卷 / 01期
关键词：
D O I：
10.1134/1.1595212
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The effect of acidification of water-ethanol solutions of cyclometalated Pt(II) and Pd(II) complexes with ethylenediamine and cyanide ligands is studied. It is found that, unlike the ethylenediamine complexes, the cyclometalated complexes with cyanide ligands are unstable and undergo irreversible decyclometalation. (C) 2003 MAIK "Nauka/Interperiodica".
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页码：49 / 51
页数：3
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