BIOCATALYSIS IN ORGANOSULFUR CHEMISTRY

被引：19

作者：

Kielbasinski, Piotr ^{[1
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, Dept Heteroorgan Chem, PL-90363 Lodz, Poland

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2011年 / 186卷 / 05期

关键词：

Asymmetric synthesis; chiral organosulfur compounds; desymmetrization; enzymes; kinetic resolution; stereoselectivity; ENZYME-PROMOTED DESYMMETRISATION; CATALYZED KINETIC RESOLUTION; MICHAEL ADDITION; FACILE ROUTE; ACTIVE-SITE; LIPASE; HYDROLYSIS; PROMISCUITY; SULFOXIDE; NITRILASE;

D O I：

10.1080/10426507.2010.541397

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enzymes, which are very efficient catalysts developed by nature to control chemical transformations in vivo, are also capable of adopting non-natural substrates, among them heteroorganic derivatives, and are also capable of working in non-aqueous media. Being intrinsically chiral, enzymes recognize any type of chirality of the substrates. This feature has been utilized for the stereoselective transformations of a variety of organosulfur compounds, resulting in the preparation of chiral non-racemic sulfur products.

引用

页码：1104 / 1118

页数：15

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