Preparation of 2,3-epoxycycloalkanones from bicyclo [n.1.0]alkan-1-ols

被引：15
|
作者：
Barnier, JP [1 ]
Morisson, V [1 ]
Blanco, L [1 ]
机构：
[1] CNRS, Inst Chim Mol Orsay, Lab Carbocycles, F-91405 Orsay, France
来源：
SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 03期
关键词：
D O I：
10.1081/SCC-100000523
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Copper- or iron-catalyzed oxidative rearrangement of bicyclo[n.1.0]alkan-1-ols yields 3-hydroperoxycycloalkanones and/or bicyclic peroxyhemiketals, which are transformed into 2,3-epoxy-cycloalkanones by treatment with a base.
引用
收藏
页码：349 / 357
页数：9
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