Unprecedented rearrangement of molybdenum(VI) oxide to (μ2-oxido)bis[dioxidomolybdenum(VI)] hexamolybdate

被引：12
|
作者：
Pedrosa, Maria R. [1 ]
Aguado, Rafael [1 ]
Diez, Virginia [1 ]
Escribano, Jaime [1 ]
Sanz, Roberto [1 ]
Arnaiz, Francisco J. [1 ]
机构：
[1] Univ Burgos, Dept Quim, Burgos 09001, Spain
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 25期
关键词：
molybdenum; hexamolybdates; O ligands; polyoxometalates; ADDITION-COMPOUNDS; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; ORGANOIMIDO DERIVATIVES; COMPLEX; DICHLORODIOXOMOLYBDENUM(VI); POLYOXOMETALATE; REACTIVITY;
D O I：
10.1002/ejic.200700653
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
yMoO(2)(acac)2 reacts with water, amides, sulfoxides, and phosphane oxides in aqueous methanol, under mild conditions, to afford a new family of molybdates of composition [Mo2O5L6]-[Mo6O1]9 (L = H2O, dimethylformamide, dimethylacetamide, dimethyl sulfoxide, dibutyl sulfoxide, tributylphosphane oxide, triphenylphosphane oxide, hexamethylphosphoramide). The crystal and molecular structures of the two first structurally characterized (mu(2)-oxido)bis[dioxidomolybdenum(VI)] hexamolybdates were established by X-ray diffraction analysis.
引用
收藏
页码：3952 / 3954
页数：3
相关论文
共 50 条
  • [21] Interaction of Nd2MoO5 with molybdenum(VI) oxide
    Fortal'nova, EA
    Safronenko, MG
    Bogatov, YE
    Kurilkin, VV
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2000, 45 (10) : 1591 - 1593
  • [22] Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI)
    Li, Zhen-Fang
    Zhang, Bi-Song
    Wu, Chang-Sheng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M741 - U535
  • [23] EFFECT OF AMINES ON THE EPOXIDATION OF ALKENES WITH H2O2 IN THE PRESENCE OF MOLYBDENUM(VI) OXIDE-BIS (TRIBUTYLTIN) OXIDE CATALYSTS
    KAMIYAMA, T
    INOUE, M
    ENOMOTO, S
    CHEMISTRY LETTERS, 1989, (07) : 1129 - 1130
  • [24] Bis[(2,3,6,7,12,13,16,17-octaethylporphycenato)oxomolybdenum(V)] hexamolybdate(VI)
    Maeda, Daisuke
    Aritome, Isao
    Shimakoshi, Hisashi
    Hisaeda, Yoshio
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M1272 - M1274
  • [25] MOLYBDENUM(VI) AND TUNGSTEN(VI) COMPLEXES OF SUBSTITUTED THIOSEMICARBAZIDES .2.
    SENGUPTA, SK
    KUMAR, S
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1983, 22 (03): : 257 - 258
  • [26] {5,5′-Bis(diethylamino)-2,2′-[(2,2-dimethylpropane-1,3-diyl) bis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI)
    Kargar, Hadi
    Kia, Reza
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1348 - U430
  • [27] Rare Examples of Biomimicking Molybdenum(VI) Catalysed Peroxidative Bromination of the Organic Substrates that Coordinate to the Oxido-Diperoxido Mo(VI) Centre
    Patra, Swarup
    Mukherjea, Kalyan K.
    CHEMISTRYSELECT, 2017, 2 (01): : 521 - 526
  • [28] Molybdenum(VI) bis-imido Complexes of Dipyrromethene Ligands
    Locher, Jan
    Watt, Fabian A.
    Neuba, Adam G.
    Schoch, Roland
    Munz, Dominik
    Hohloch, Stephan
    INORGANIC CHEMISTRY, 2020, 59 (14) : 9847 - 9856
  • [29] Isolated Molybdenum(VI) and Tungsten(VI) Oxide Species on Partly Dehydroxylated Silica: A Computational Perspective
    Kurleto, Kamil
    Tielens, Frederik
    Handzlik, Jaroslaw
    JOURNAL OF PHYSICAL CHEMISTRY C, 2020, 124 (05): : 3002 - 3013
  • [30] PREPARATION OF SALICYLATO AND NITROSALICYLATO DERIVATIVES OF BIS-PI-CYCLOPENTADIENYL MOLYBDENUM(VI)-OXO DICHLORIDE AND BIS-PI-INDENYL MOLYBDENUM(VI)-OXO DICHLORIDE
    GOYAL, KC
    KHOSLA, BD
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1980, 57 (02) : 124 - 126
12345