Structure Determination of Neptunium(VI) μ3-Hydroxobenzoate, [(NPO2)2(μ3-OH)2(H5C6COO)2]•2H2O

被引：5
|
作者：
Charushnikova, Iraida A. [1 ]
Krot, Nikolai N. [1 ]
Makarenkov, Vadim I. [1 ]
机构：
[1] Russian Acad Sci, AN Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 17期
关键词：
CRYSTAL-STRUCTURE; BENZOATE; COMPLEXES; PROPERTY; ACID;
D O I：
10.1021/ic100951y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Neptunium(VI) benzoate with mu(3)-OH- has been isolated and studied by the X-ray method. The main structural motive in the crystal is corrugated ribbons [(NpO2)(2)(mu(3)-OH)(2)(C7H5O2)(2)](n) extended along the c axes in which three neptunium pentagonal bipyramids are linked through the mu(3)-OH- ligand. The benzoate ions are arranged at both sides of the ribbons, and each anion binds two adjacent NpO2. The water molecules are arranged in the channels along the c axis.
引用
收藏
页码：7611 / 7613
页数：3
相关论文
共 50 条
  • [21] Synthesis and Crystal Structure of Ni3（admt）6（NCS）6·C2H5OH·2H2O
    LIU Jia Cheng SONG You ZHUANG Jin Zhong * YOU Xiao Zeng (Coordination Chemistry Institute
    结构化学, 2000, (02) : 81 - 85
  • [22] Synthesis and crystal structure of Ni3(admt)6(NCS)6 • C2H5OH • 2H2O
    Liu, JC
    Song, Y
    Zhuang, JZ
    You, XZ
    Huang, XY
    Huang, ZX
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (02) : 81 - 85
  • [23] Crystal structures of Np(VI) and Pu(VI) phthalates [NpO2{(OOC)2C6H4}H2O]•1/3H2) and [PuO2{(OOC)2C6H}H2O4]•H2O
    Grigoriev, MS
    Antipin, MY
    Krot, NN
    Bessonov, AA
    RADIOCHIMICA ACTA, 2004, 92 (07) : 405 - 409
  • [24] Preparation of organozirconium aromatic compounds in mixed aqueous-organic solvents: X-ray structures of [Cp2ZrCl(μ2-O′,O"C-C6H5)], [(CpZr)3(μ2-O′,O"C-C6H3Cl2)3(μ3-OH)(μ2-OH)3](Cl2C6H3COO)2, and [(CpZr)3(μ2-O′,O"C-C6H4Cl)3(μ3-OH)(μ2-OH)3]Cl2•CH2Cl2
    Li, Jinling
    Gao, Ziwei
    Han, Li
    Gao, Lingxiang
    Zhang, Caiyun
    Tikkanen, Wayne
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (21) : 3444 - 3451
  • [25] Synthesis and the crystal structure of aqua-dioxo-nitrato-(2,2′,6′,2″-terpyridine)-neptunium(V) [NpO2(NO3)(terpy)(H2O)]
    N. A. Budantseva
    G. B. Andreev
    A. M. Fedoseev
    M. Yu. Antipin
    J.-C. Krupa
    Crystallography Reports, 2003, 48 : 58 - 60
  • [26] Crystal Structure and Stability in Aqueous Solutions of Na0.5[NpO2(OH)1.5]•0.5H2O and Na[NpO2(OH)2]
    Fellhauer, David
    Lee, Jun-Yeop
    DiBlasi, Nicole A.
    Walter, Olaf
    Gaona, Xavier
    Schild, Dieter
    Altmaier, Marcus
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (21) : 9217 - 9221
  • [27] Synthesis and the crystal structure of aqua-dioxo-nitrato-(2,2′,6′,2"-terpyridine)-neptunium(V) [NpO2(NO3)(Terpy)(H2O)]
    Budantseva, NA
    Andreev, GB
    Fedoseev, AM
    Antipin, MY
    Krupa, JC
    CRYSTALLOGRAPHY REPORTS, 2003, 48 (01) : 58 - 60
  • [28] Magnetic property of neptunyl (+2) complex NpO2(C6H7O2)2(C5H5N)
    Nakamura, A.
    Nakada, M.
    Nakamoto, T.
    Kitazawa, T.
    Takeda, M.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 310 (02) : 1447 - 1449
  • [29] Molecular magnetism of neptunyl (+2) complex NpO2(C6H7O2)2(C5H5N)
    Nakamura, Akio
    Nakada, Masami
    Nakamoto, Tadahiro
    Kitazawa, Takafumi
    Takeda, Masuo
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2006, 75 : 146 - 148
  • [30] Crystal Structure and Electronic Absorption Spectrum of Double Neptunium(V) Phthalate Co(NH3)6NpO2[(OOC)2C6H4]2·2H2O
    I. A. Charushnikova
    N. N. Krot
    Z. A. Starikova
    Radiochemistry, 2001, 43 (5) : 496 - 501
12345