Nickel and palladium catalyzed Kumada-Tamao-Corriu cross-coupling reactions: scope and recent advances

被引：5

作者：

Dahadha, Adnan A. ^{[1
]}

Aldhoun, Mohammad M. ^{[2
]}

机构：

[1] Philadelphia Univ, Fac Sci, Biotechnol Dept, POB 19392, Amman, Jordan

[2] Philadelphia Univ, Fac Pharm, POB 19392, Amman, Jordan

来源：

ARKIVOC | 2018年

关键词：

Kumada coupling; nickel catalysis; palladium catalysis; Grignard reagents; biaryls; FUNCTIONALIZED GRIGNARD-REAGENTS; NONACTIVATED ALKYL-HALIDES; ARYL CHLORIDES; EXCHANGE-REACTION; KETONE SYNTHESIS; BOND ACTIVATION; ORGANIC HALIDES; HETEROARYL; PD; ORGANOZINC;

D O I：

10.24820/ark.5550190.p010.746

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The nickel and palladium catalyzed Kumada-Tamao-Corriu cross-coupling reaction is a powerful method for the formation of carbon-carbon bonds, employed in many large-scale applications in the pharmaceutical and electronic material industries. Kumada cross-coupling is the reaction of an organohalide substrate with a Grignard reagent to produce the corresponding coupled product using a palladium or nickel catalyst. This review covers key developments in Kumada cross-coupling reactions over the past ten years. [GRAPHICS]

引用

页码：234 / 253

页数：20

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