Green and catalyst-free synthesis of aminoanthraquinone derivatives in solvent-free conditions

被引：1

作者：

Sardashti-Birjandi, Arezoo ^{[1
]}

Mollashahi, Ebrahim ^{[1
]}

Maghsoodlou, Malek Taher ^{[1
]}

Yazdani-Elah-Abadi, Afshin ^{[2
]}

机构：

[1] Univ Sistan & Baluchestan, Fac Sci, Dept Chem, POB 98135-674, Zahedan, Iran

[2] Islamic Azad Univ, Yazd Branch, Young Researchers & Elite Club, Yazd, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2021年 / 47卷 / 09期

关键词：

Multicomponent reactions; Anthraquinone; Catalyst-free; Triethyl orthoformate; ONE-POT SYNTHESIS; ANTHRAQUINONE DERIVATIVES; REUSABLE CATALYST; DEGRADATION; NANOCOMPOSITE; DYES; CHEMISTRY; EFFICIENT; REMOVAL; MEDIA;

D O I：

10.1007/s11164-021-04485-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, new derivatives of aminoanthraquinone have been synthesized via one-pot three-component condensation reaction of 1- and 2-amino anthraquinones, triethyl orthoformate and CH-acid compounds without using any solvent or catalyst in mild temperature (50 degrees C). This simple and efficient method yields the desired products in short reaction time (14-50 min) and good to excellent yields (85-96%). Moreover, chemical structures of synthesized products have been entirely confirmed by FT-IR, H-1 and (CNMR)-C-13 and mass spectroscopy and melting points.

引用

页码：3597 / 3608

页数：12

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