Zintl-compounds with gold:: M3AuSn4 with M = K, Rb, Cs and M3AuPb4 with M = Rb, Cs

被引：0
|
作者：
Zachwieja, U [1 ]
Muller, J [1 ]
Wlodarski, J [1 ]
机构：
[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 05期
关键词：
alkali metal auride stannide; alkali metal auride plumbide; Zintl-compounds; synthesis; crystal structure;
D O I：
10.1002/(SICI)1521-3749(199805)624:5<853::AID-ZAAC853>3.0.CO;2-N
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Silver coloured, brittle single crystals of the compounds M3AuSn4 with M = K, Rb, Cs and M3AuPb4 with M = Rb, Cs were synthesized by reactions of alkali metal azides (MN3) with gold sponge and tin (lead) powder at T = 923 K. The structures of the isotypic compounds (space group Pmmn, Z = 2) were determined from X-ray single-crystal diffractometry data (see "Inhaltsubersicht"). The Zintl-compounds M3AuE(14)(4) with E(14) = Sn, Ph contain (1)(infinity)[AuE(14)(4)]-chains with P-4-analogous E(14)(4)-tetrahedra which are connected by mu(2)-bridging gold atoms.
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页码：853 / 858
页数：6
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