Electronic communication in [Co2(CO)6]2-diyne and [Co2(CO)4(dppm)]2-diyne complexes

被引：0

作者：

Osella, D ^{[1
]}

Milone, L ^{[1
]}

Nervi, C ^{[1
]}

Ravera, M ^{[1
]}

机构：

[1] Univ Turin, Dipartimento Chim IFM, I-10125 Turin, Italy

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 1998年 / 10期

关键词：

electrochemistry; mixed-valent compounds; alkynecobalt complexes; through-bond interactions; through-space interactions;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrochemical behaviour of the [Co-2(CO)(6)](2)(mu-R-C=C-L-C=C-R) and [Co-2(CO)(4)(dppm)](2)(mu-R-C=C-L-C=C-R) series is reported. Qualitative evidence suggests that both through-space and through-bond interactions are operating with different relative weight depending on the spacer L.

引用

页码：1473 / 1477

页数：5

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