Bromido[(1,2,5,6-η)-1,3,5,7-cyclooctatetraene]methylplatinum(II)

被引:1
|
作者
Song, Ah-Ran
Hwang, In-Chul
Ha, Kwang [1 ]
机构
[1] Chonnam Natl Univ, Ctr Funct Nano Fine Chem, Sch Appl Chem Engn, Kwangju 500757, South Korea
[2] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea
关键词
D O I
10.1107/S1600536807043279
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [PtBr(CH3)(C8H8)], the PtII centre lies in a square-planar environment defined by the Br and methyl C atoms and the midpoints of the two π-coordinated double bonds of 1,3,5,7-cyclo-octa-tetra- ene. Because of the different trans influences of the Br atom and the methyl group, the Pt - C bonds trans to the methyl group are longer than those trans to the Br atom. © International Union of Crystallography 2007.
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页码:M2484 / U469
页数:9
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