Spectrophotometric determination of microgram quantities of palladium (II) in alloys

被引：0
|
作者：
Pape, Gowd C. T. [1 ]
Srinivas, J. [1 ]
Rao, Suryanarayana, V [1 ]
机构：
[1] Sri Krishnadevaraya Univ, Dept Chem, Anantapur 515003, Andhra Pradesh, India
来源：
RESEARCH JOURNAL OF CHEMISTRY AND ENVIRONMENT | 2008年 / 12卷 / 01期
关键词：
spectrophotometry; furfuraldehyde; thiosemicarbazone; Pd(II) ion;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A method for the spectrophotometric determination of Pd(II) has been developed by using furfuraldehyde thiosemicarbazone (FFTSC) as complexing agent. Pd(II) reacts with FFTSC in the pH range 1 to 5 to form yellow coloured solution. The complex shows maximum absorption in a buffer solution of pH 1. lambda(max) is 360.5 nm. The composition of the complex is 1:4(M:L). Beer's law is obeyed in the range 0.170 mu g/ml to 1.703 mu g/ml. The molar absorptivity and Sandel sensitivity are calculated as 3.9911 X 10(4) L mol(-1) cm(-1) and 0.0026664 mu g cm(-2) respectively. The method has been. successfully applied for Pd(II) determination in alloys.
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页码：58 / 60
页数：3
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