Formaldehyde sensing properties of electrospun NiO-doped SnO2 nanofibers

Formaldehyde is a kind of hazardous gases dangerous to human health. Hence, gas sensor is an essential device to monitor formaldehyde in air, especially in indoor ambient. Semiconductor metal oxides are studied as gas-sensing material to detect most of key gases for decade years. For the purpose of actual application and meeting a variety of conditions, diverse additives added into host material are expected to improve the performance of gas sensors. The formaldehyde gas-sensing characteristics of undoped and NiO-doped SnO(2) (NSO) nanofibers synthesized via a simple electrospinning method were investigated in this study. It is noticed that the addition of NiO causes the distortion at the surface of SnO(2) nanofibers, which is responsible to adjust activation energy, grain sizes and chemical states of host material. The sensors fabricated from NSO nanofibers exhibited good formaldehyde sensing properties at operating temperature 200 degrees C, and the minimum-detection-limit was down to 0.08 ppm. The response time and recovery time of the sensors were about 50 s and 80 s to 10 ppm formaldehyde, respectively. The sensor shows a good long-term stability in 90 days. The simple preparation and excellent properties significantly advance the viability of electrospun nanofibers as gas sensing materials. The sensing mechanisms of NSO nanofibers to formaldehyde were discussed. The results indicated that NSO nanofibers could be used as a candidate to fabricate formaldehyde sensors in practice. (C) 2011 Elsevier B.V. All rights reserved.