Metal-porphyrin in epoxidation of olefins: Recent advances

被引：10
|
作者：
Ahmad, Irshad [1 ]
Shagufta [1 ]
Rehman, Sadia [2 ]
机构：
[1] Amer Univ Ras Al Khaimah, Sch Arts & Sci, Dept Math & Nat Sci, Ras Al Khaymah, U Arab Emirates
[2] Amer Univ Ras Al Khaimah, Sch Engn, Dept Chem Engn, Ras Al Khaymah, U Arab Emirates
来源：
TETRAHEDRON | 2022年 / 104卷
关键词：
Asymmetric; Catalysis; Epoxidation; Heterogeneous; Homogeneous; Porphyrins; OXYGEN-ATOM TRANSFER; ASYMMETRIC EPOXIDATION; ENANTIOSELECTIVE EPOXIDATION; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; HIGHLY EFFICIENT; MN-PORPHYRIN; UNFUNCTIONALIZED OLEFINS; CHIRAL METALLOPORPHYRINS; MANGANESE-PORPHYRINS;
D O I：
10.1016/j.tet.2021.132604
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The application of cytochrome P-450 inspired metal-porphyrin catalysts within the oxidation reaction, predominantly in olefin epoxidation, has advanced as a trending topic in research. A strenuous effort has been made to summarize the catalytic activity of the most promising metal-porphyrin-based homogeneous and heterogeneous catalysts reported in the literature for the various olefins and cyclic enones epoxidation. This mini-review provides a practical and comprehensive vision for understanding homogeneous and heterogeneous metalloporphyrin-based catalysis and covers the recent advancement of a modern, novel catalytic framework for oxidation chemistry. (C) 2021 Elsevier Ltd. All rights reserved.
引用
收藏
页数：22
相关论文
共 50 条
  • [41] Energy transfer on demand: Photoswitch-directed behavior of metal-porphyrin frameworks
    Shustova, Natalia B., 1600, American Chemical Society (136):
  • [42] Recent Advances on Tandem Hydroformylation of Olefins
    Wang, Peng
    Liu, Huan
    Yang, Da
    PROGRESS IN CHEMISTRY, 2022, 34 (05) : 1076 - 1087
  • [43] METAL-PORPHYRIN INTERACTIONS .3. DISSOCIATIVE-INTERCHANGE MECHANISM FOR METAL-ION INCORPORATION INTO PORPHYRIN MOLECULES
    HAMBRIGH.P
    CHOCK, PB
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (10) : 3123 - 3131
  • [44] Recent Advances in Radical Dioxygenation of Olefins
    Bag, Raghunath
    De, Pinaki Bhusan
    Pradhan, Sourav
    Punniyamurthy, Tharmalingam
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 2017 (37) : 5424 - 5438
  • [45] Metal-porphyrin orbital interactions in highly saddled low-spin iron(III) porphyrin complexes
    Ohgo, Yoshiki
    Hoshino, Akito
    Okamura, Tomoya
    Uekusa, Hidehiro
    Hashizume, Daisuke
    Ikezaki, Akira
    Nakamura, Mikio
    INORGANIC CHEMISTRY, 2007, 46 (20) : 8193 - 8207
  • [46] Recent Advances on Porphyrin and Metalloporphyrin Chemistry
    Rivera Garcia, Ernesto
    Solladie, Nathalie
    Zaragoza Galan, Gerardo
    CURRENT ORGANIC CHEMISTRY, 2022, 26 (06) : 551 - 552
  • [47] ANYL 110-Spectroscopic investigation of metal-porphyrin complexes in silica aerogels
    Hebert, Paul C.
    Baig, Shazia
    Anderson, Ann M.
    Carroll, Mary K.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [48] Recent advances in the epoxidation of perfluoro- and hydrofluoroolefins
    Brandt, Drew
    Petrov, Viacheslav
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [49] THE PROTECTIVE ACTION OF CRUDE PETROLEUM FOR METAL-PORPHYRIN COMPLEXES EXPOSED TO GAMMA IRRADIATION
    DUNNING, HN
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (19) : 5320 - 5321
  • [50] Polymeric metal complex catalyzed enantioselective epoxidation of olefins
    Dhal, PK
    De, BB
    Sivaram, S
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 177 (01) : 71 - 87
12345