New approach to λ5-phosphinines

被引：16

作者：

Kostyuk, AN ^{[1
]}

Svyaschenko, YV ^{[1
]}

Volochnyuk, DM ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev, Ukraine

来源：

TETRAHEDRON | 2005年 / 61卷 / 39期

关键词：

lambda(5)-phosphinines; phosphonium salts; phosphorylated enamines; DMADMF;

D O I：

10.1016/j.tet.2005.07.069

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel approach to lambda(5)-phosphinines has been discovered. Phosphonium salts bearing an alkyl group and the residue of beta-dialkylaminocrotonic acid react with DMADMF affording lambda(5)-phosphinines. A plausible mechanism of the reaction is offered. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：9263 / 9272

页数：10

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