New approach to λ5-phosphinines

被引：16
|
作者：
Kostyuk, AN [1 ]
Svyaschenko, YV [1 ]
Volochnyuk, DM [1 ]
机构：
[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev, Ukraine
来源：
TETRAHEDRON | 2005年 / 61卷 / 39期
关键词：
lambda(5)-phosphinines; phosphonium salts; phosphorylated enamines; DMADMF;
D O I：
10.1016/j.tet.2005.07.069
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel approach to lambda(5)-phosphinines has been discovered. Phosphonium salts bearing an alkyl group and the residue of beta-dialkylaminocrotonic acid react with DMADMF affording lambda(5)-phosphinines. A plausible mechanism of the reaction is offered. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：9263 / 9272
页数：10
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