The hydroxyalkylation of phenol with formaldehyde over mesoporous M(Al, Zr, Al-Zr)-SBA-15 catalysts: The effect on the isomer distribution of bisphenol F

被引：18

作者：

Tan, Ying ^{[1
]}

Li, Yongfei ^{[1
]}

Wei, Yuanfeng ^{[1
]}

Wu, Zhimin ^{[1
]}

Yan, Jiaqi ^{[1
]}

Pan, Langsheng ^{[1
]}

Liu, Yuejin ^{[1
]}

机构：

[1] Xiangtan Univ, Sch Chem Engn, Xiangtan 411105, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2015年 / 67卷

基金：

中国国家自然科学基金;

关键词：

M-SBA-15; Hydroxyalkylation; Bisphenol F; Isomer distribution; Regulation; IRON-OXIDE NANOPARTICLES; AMORPHOUS SILICA-ALUMINA; MOLECULAR-SIEVES; ALKYLATION; SITES;

D O I：

10.1016/j.catcom.2015.03.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mesoporous M(Al, Zr, Al-Zr)-SBA-15 catalysts prepared by a direct method were used for the hydroxyalkylation of phenol with formaldehyde to bisphenol F in the presence of water. The results showed that M(20)-SBA-15 with the Si/M molar ratio of 20 exhibited higher catalytic activity. The isomer distribution of bisphenol F could be regulated in the hydroxyalkylation of phenol with formaldehyde by changing the Al/Zr ratio in M(20)-SBA-15 catalysts. Al(20)-SBA-15 was in favor of the formation of 4,4'-isomer, whereas Zr(20)-SBA-15 was in favor of the formation of 2,4'- and 2,2'-isomers. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：21 / 25

页数：5

共 20 条

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