The hydroxyalkylation of phenol with formaldehyde over mesoporous M(Al, Zr, Al-Zr)-SBA-15 catalysts: The effect on the isomer distribution of bisphenol F

被引：18

作者：

Tan, Ying ^{[1
]}

Li, Yongfei ^{[1
]}

Wei, Yuanfeng ^{[1
]}

Wu, Zhimin ^{[1
]}

Yan, Jiaqi ^{[1
]}

Pan, Langsheng ^{[1
]}

Liu, Yuejin ^{[1
]}

机构：

[1] Xiangtan Univ, Sch Chem Engn, Xiangtan 411105, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2015年 / 67卷

基金：

中国国家自然科学基金;

关键词：

M-SBA-15; Hydroxyalkylation; Bisphenol F; Isomer distribution; Regulation; IRON-OXIDE NANOPARTICLES; AMORPHOUS SILICA-ALUMINA; MOLECULAR-SIEVES; ALKYLATION; SITES;

D O I：

10.1016/j.catcom.2015.03.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mesoporous M(Al, Zr, Al-Zr)-SBA-15 catalysts prepared by a direct method were used for the hydroxyalkylation of phenol with formaldehyde to bisphenol F in the presence of water. The results showed that M(20)-SBA-15 with the Si/M molar ratio of 20 exhibited higher catalytic activity. The isomer distribution of bisphenol F could be regulated in the hydroxyalkylation of phenol with formaldehyde by changing the Al/Zr ratio in M(20)-SBA-15 catalysts. Al(20)-SBA-15 was in favor of the formation of 4,4'-isomer, whereas Zr(20)-SBA-15 was in favor of the formation of 2,4'- and 2,2'-isomers. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：21 / 25

页数：5

共 20 条

[1] Short-channeled mesoporous Zr-Al-SBA-15 as a highly efficient catalyst for hydroxyalkylation of phenol with formaldehyde to bisphenol F
Wei, Yuanfeng
Li, Yongfei
Tan, Ying
Wu, Zhimin
Pan, Langsheng
Liu, Yuejin
CHEMICAL ENGINEERING JOURNAL, 2016, 298 : 271 - 280
[2] Hydroxyalkylation of phenol to bisphenol F over heteropolyacid catalysts: The effect of catalyst acid strength on isomer distribution and kinetics
Wu, Xianzhang
Liu, Yutang
Liu, Ran
Wang, Longlu
Lu, Yanbing
Xia, Xinnian
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 481 : 75 - 81
[3] Effect of the Incorporation of Al, Ti, and Zr on the Cracking and Hydrodesulfurization Activity of NiMo/SBA-15 Catalysts
Rayo, P.
Ramirez, J.
Rana, M. S.
Ancheyta, J.
Aguilar-Elguezabal, A.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (03) : 1242 - 1248
[4] Effect of heteroatom doping on surface acidity and hydrophilicity of Al, Ti, Zr-doped mesoporous SBA-15
Szczodrowski, Karol
Prelot, Benedicte
Lantenois, Sebastien
Douillard, Jean-Marc
Zajac, Jerzy
MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 124 (1-3) : 84 - 93
[5] Enhanced ethylene production by dehydration of ethanol over Al/SBA-15 mesoporous catalysts
Salem, Heba M.
Mohamed, Rasha S.
Alkahlawy, Amal A.
Gobara, Heba M.
Hassan, Amir E. A.
Hassan, Salah A.
JOURNAL OF POROUS MATERIALS, 2019, 26 (03) : 735 - 745
[6] Enhanced ethylene production by dehydration of ethanol over Al/SBA-15 mesoporous catalysts
Heba M. Salem
Rasha S. Mohamed
Amal A. Alkahlawy
Heba M. Gobara
Amir E. A. Hassan
Salah A. Hassan
Journal of Porous Materials, 2019, 26 : 735 - 745
[7] SBA-15 modified with Al, Ti, or Zr as supports for highly active NiW catalysts for HDS
Lizama, Lilia Y.
Klimova, Tatiana E.
JOURNAL OF MATERIALS SCIENCE, 2009, 44 (24) : 6617 - 6628
[8] SBA-15 modified with Al, Ti, or Zr as supports for highly active NiW catalysts for HDS
Lilia Y. Lizama
Tatiana E. Klimova
Journal of Materials Science, 2009, 44 : 6617 - 6628
[9] Catalytic activity of SBA-15 supported Ni catalyst in CH4 dry reforming: Effect of Al, Zr, and Ti co-impregnation and Al incorporation to SBA-15
Okutan, Cigdem
Arbag, Huseyin
Yasyerli, Nail
Yasyerli, Sena
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (27) : 13911 - 13928
[10] Sites for CO2 activation over amine-functionalized mesoporous Ti(Al)-SBA-15 catalysts
Srivastava, R
Srinivas, D
Ratnasamy, P
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 90 (1-3) : 314 - 326

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