Synthesis by Stille cross-coupling procedure and electrochemical characterization of branched polymers based on substituted 1,3,5-triarylbenzenes

被引：3

作者：

Idzik, Krzysztof R. ^{[1
]}

Beckert, Rainer ^{[1
]}

Tauscher, Eric ^{[1
]}

Ledwon, Przemyslaw ^{[2
]}

Golba, Sylwia ^{[2
]}

Lapkowski, Mieczyslaw ^{[2
,3
]}

Rapta, Peter ^{[4
,5
]}

Dunsch, Lothar ^{[6
]}

Frydel, Jaroslaw ^{[6
]}

机构：

[1] Jena FSU, Inst Organ & Macromol Chem, D-07743 Jena, Germany

[2] Silesian Technol Univ, Fac Chem, PL-44100 Gliwice, Poland

[3] Polish Acad Sci, Ctr Polymer & Corbon Mat, PL-44121 Gliwice, Poland

[4] Grp Electrochem & Conduct Polymer, Leibniz Inst Solid State & Mat Res, D-01171 Dresden, Germany

[5] Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Dept Phys Chem, SK-81237 Bratislava, Slovakia

[6] Tech Univ Darmstadt, Eduard Zintl Inst Anorganische Physik, Petersenstr 30, D-64287 Darmstadt, Germany

来源：

OPTOELECTRONIC MATERIALS, PTS 1AND 2 | 2010年 / 663-665卷

关键词：

Stille coupling procedure; Electrochemical polymerization; Hyperbranched polymers; Cyclic voltammetry; SOLAR-CELLS; DESIGN;

D O I：

10.4028/www.scientific.net/MSF.663-665.876

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

A series of various substituted 1,3,5-triarylbenzenes, 2,4,6-triaryl-1-phenoles, 1,3,5-triaryl-1-methoxybenzenes and 2,4,6-triaryl-1,3,5-trimethoxybenzenes were synthesized by a Stille cross-coupling procedure. Their structures were confirmed by H-1 NMR, C-13 NMR, and elemental analysis. Containing thienyl, fury! and EDOT groups polymers obtained in the process of electropolymerization could be carefully considered as a building material in a wide range of organic-electronic devices. We compare properties of monomers and related polymers depending on aryls moieties and their influence of hydroxyl and methoxyl groups attached to the central benzene core.

引用

页码：876 / +

页数：2

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