Isolation and FTIR analysis of endohedral L3-xMxN@C80 (0≤x≤3) fullerenes

被引：0

作者：

Krause, M ^{[1
]}

Noack, J ^{[1
]}

Marczak, R ^{[1
]}

Georgi, P ^{[1
]}

Dunsch, L ^{[1
]}

机构：

[1] Leibniz Inst Solid State & Mat Res Dresden, D-01171 Dresden, Germany

来源：

MOLECULAR NANOSTRUCTURES | 2003年 / 685卷

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Trimetal nitride (M3N) fullerenes play a special role among the endohedral fullerenes due to a high abundance in the soot extract and the ability to stabilize non IPR fullerenes [1, 2]. The recent analysis of endohedral Sc3N@C-80 fullerene revealed a crucial role of the Sc3N cluster for the overall stability [3]. This work was now extended to other M3N@C-80 structures with uniform and mixed metal clusters, where M = Y, Tb, Ho, and Er. FTIR spectra confirmed the preference of trimetal nitrides to the I-h-C-80 isomer. Moreover our data point to a strong influence of the metal on the structure of the endohedral clusters and the stability of the clusterfullerenes as a whole.

引用

页码：50 / 53

页数：4

共 50 条

[31] Isolation and structural characterization of the endohedral fullerene Sc3N@C78
Olmstead, MM
de Bettencourt-Dias, A
Duchamp, JC
Stevenson, S
Marciu, D
Dorn, HC
Balch, AL
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001, 40 (07) : 1223 - +
[32] Theoretical studies of structures and stabilities of endohedral fullerenes X0/n+@C32 (X = H, Li, Na, K, Be, Mg, Ca, B, Al, C, Si, N, P, n = 1-3)
Sun, Lili
Chang, Yingfei
Hong, Bo
Wang, Rongshun
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2007, 107 (05) : 1241 - 1247
[33] A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N@C80
Iezzi, EB
Duchamp, JC
Harich, K
Glass, TE
Lee, HM
Olmstead, MM
Balch, AL
Dorn, HC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (04) : 524 - 525
[34] Tunable Charge-Transport Properties of Ih-C80 Endohedral Metallofullerenes: Investigation of La2@C80, Sc3N@C80, and Sc3C2@C80
Sato, Satoru
Seki, Shu
Luo, Guangfu
Suzuki, Mitsuaki
Lu, Jing
Nagase, Shigeru
Akasaka, Takeshi
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (28) : 11681 - 11686
[35] Molecular and Spin Dynamics in the Paramagnetic Endohedral Fullerene Gd3N@C80
Nafradi, B.
Antal, A.
Pasztor, A.
Forro, L.
Kiss, L. F.
Feher, T.
Kovats, E.
Pekker, S.
Janossy, A.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (22): : 3291 - 3296
[36] Crystallographic characterization and structural analysis of the first organic functionalization product of the endohedral fullerene SC3N@C80
Lee, HM
Olmstead, MM
Iezzi, E
Duchamp, JC
Dorn, HC
Balch, AL
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (14) : 3494 - 3495
[37] DFT Analysis of the Electronic and Structural Properties of Lanthanide Nitride Cluster Fullerenes Ln3N@C80
Martinez-Flores, Cesar
Basiuk, Vladimir A.
INORGANICS, 2023, 11 (05)
[38] Preparation and structural characterization of the Ih and the D5h isomers of the endohedral fullerenes Tm3N@C80:: Icosahedral C80 cage encapsulation of a trimetallic nitride magnetic cluster with three uncoupled Tm3+ ions
Zuo, Tianming
Olmstead, Marilyn M.
Beavers, Christine M.
Balch, Alan L.
Wang, Guangbin
Yee, Gordon T.
Shu, Chunying
Xu, Liaosa
Elliott, Bevan
Echegoyen, Luis
Duchamp, James C.
Dorn, Harry C.
INORGANIC CHEMISTRY, 2008, 47 (12) : 5234 - 5244
[39] An ab initio investigation on the endohedral metallofullerene Gd3 N- C80
Qian, M.C.
Khanna, S.N.
Journal of Applied Physics, 2007, 101 (09):
[40] Synthesis of Silylene-Bridged Endohedral Metallofullerene Lu3N@Ih-C80
Sato, Kumiko
Kako, Masahiro
Suzuki, Mitsuaki
Mizorogi, Naomi
Tsuchiya, Takahiro
Olmstead, Marilyn M.
Balch, Alan L.
Akasaka, Takeshi
Nagase, Shigeru
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (38) : 16033 - 16039

← 1 2 3 4 5 →