Robust CoAl Alloy: Highly Active, Reusable and Green Catalyst in the Hydrogenolysis of Glycerol

被引:7
|
作者
Guo Xiaoyang [1 ,2 ]
Yin Anyuan [1 ,2 ]
Guo Xiaodong [3 ]
Guo Xiuying [1 ,2 ]
Dai Weilin [1 ,2 ]
Fan Kangnian [1 ,2 ]
机构
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, State Key Lab High Field Laser Phys, Shanghai 201800, Peoples R China
基金
中国国家自然科学基金;
关键词
CoAl; biomass; glycerol; hydrogenolysis; 1,2-propanediol; CONVERSION;
D O I
10.1002/cjoc.201180281
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CoAl alloy catalyst is found, for the first time, to be highly active, selective and reusable for the synthesis of diols via the hydrogenolysis of glycerol under mild conditions. The products and the catalyst could be self-separated from the reaction system through a simple reactor.
引用
收藏
页码:1563 / 1566
页数:4
相关论文
共 50 条
  • [1] Ir-Re alloy as a highly active catalyst for the hydrogenolysis of glycerol to 1,3-propanediol
    Deng, Chenghao
    Duan, Xuezhi
    Zhou, Jinghong
    Zhou, Xinggui
    Yuan, Weikang
    Scott, Susannah L.
    CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (03) : 1540 - 1547
  • [2] Cu/boehmite: A highly active catalyst for hydrogenolysis of glycerol to 1,2-propanediol
    Wu, Zhijie
    Mao, Yuzhen
    Song, Meng
    Yin, Xiaoqian
    Zhang, Minghui
    CATALYSIS COMMUNICATIONS, 2013, 32 : 52 - 57
  • [3] An Active K-OMS-2 Supported Catalyst for Hydrogenolysis of Glycerol
    Gogoi, Pranjal
    Chilukuri, Satyanarayana
    Thirumalaiswamy, Raja
    CHEMISTRYSELECT, 2021, 6 (33): : 8700 - 8708
  • [4] Highly active metal-acid bifunctional catalyst system for hydrogenolysis of glycerol under mild reaction conditions
    Kusunoki, Y
    Miyazawa, T
    Kunimori, K
    Tomishige, K
    CATALYSIS COMMUNICATIONS, 2005, 6 (10) : 645 - 649
  • [5] Ordered mesoporous titanium phosphate material: A highly efficient, robust and reusable solid acid catalyst for acetalization of glycerol
    Miao, Zhichao
    Li, Zhenbin
    Liang, Manfen
    Meng, Jian
    Zhao, Yuzhen
    Xu, Leilei
    Mu, Jinglin
    Zhou, Jin
    Zhuo, Shuping
    Si, Weijiang
    CHEMICAL ENGINEERING JOURNAL, 2020, 381
  • [6] Highly active iridium-rhenium catalyst condensed on silica support for hydrogenolysis of glycerol to 1,3-propanediol
    Liu, Lujie
    Kawakami, Shota
    Nakagawa, Yoshinao
    Tamura, Masazumi
    Tomishige, Keiichi
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 256
  • [7] Hydrogenolysis of glycerol over a highly active CuO/ZnO catalyst prepared by an oxalate gel method: influence of solvent and reaction temperature on catalyst deactivation
    Bienholz, Arne
    Schwab, Frederick
    Claus, Peter
    GREEN CHEMISTRY, 2010, 12 (02) : 290 - 295
  • [8] Hydrogenolysis of Glycerol to Propanediols Over Highly Active Ru–Re Bimetallic Catalysts
    Lan Ma
    Dehua He
    Topics in Catalysis, 2009, 52 : 834 - 844
  • [9] Selective Hydrogenolysis of Glycerol to 1,2-Propanediol over Highly Active and Stable Cu/MgO Catalyst in the Vapor Phase
    Pandhare, Nitin Naresh
    Pudi, Satyanarayana Murty
    Biswas, Prakash
    Sinha, Shishir
    ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2016, 20 (06) : 1059 - 1067
  • [10] A highly active and reusable heterogeneous ruthenium catalyst for olefin metathesis
    Li, L
    Shi, JL
    ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (14) : 1745 - 1749