Cu/boehmite: A highly active catalyst for hydrogenolysis of glycerol to 1,2-propanediol

被引：83

作者：

Wu, Zhijie ^{[1
,2
]}

Mao, Yuzhen ^{[3
,4
]}

Song, Meng ^{[3
,4
]}

Yin, Xiaoqian ^{[3
,4
]}

Zhang, Minghui ^{[3
,4
]}

机构：

[1] China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China

[2] China Univ Petr, Key Lab Catalysis CNPC, Beijing 102249, Peoples R China

[3] Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem MOE, Tianjin 300071, Peoples R China

[4] Nankai Univ, Coll Chem, Inst New Catalyt Mat Sci, Tianjin 300071, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2013年 / 32卷

关键词：

Glycerol; 1,2-Propanediol; Boehmite; Copper; Hydrogenolysis; GAS-PHASE DEHYDRATION; PROPYLENE-GLYCOL; PRECIPITATION; HYDROGENATION; SOL;

D O I：

10.1016/j.catcom.2012.12.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Small Cu clusters (similar to 1 nm) were highly dispersed over boehmite via an aqueous chemical reduction method. In comparison with Cu/gamma-Al2O3, Cu/SiO2 and Ru/C catalyst, Cu/boehmite catalyst showed the highest conversion and selectivity of 1,2-propanediol in the hydrogenolysis of glycerol. The good conversion and selectivity are ascribed to the small size of Cu metal clusters and the Lewis acid sites of boehmite, which provides high surface concentrations of active metal sites without C-C bond cleavage activity and promotes the dehydration of glycerol to acetol as the intermediate of 1,2-propanediol, respectively. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：52 / 57

页数：6

共 50 条

[1] Cu:Al Nano Catalyst for Selective Hydrogenolysis of Glycerol to 1,2-Propanediol
Rasika B. Mane
Amol M. Hengne
Ajay A. Ghalwadkar
Subramanian Vijayanand
Pravin H. Mohite
Hari S. Potdar
Chandrashekhar V. Rode
Catalysis Letters, 2010, 135 : 141 - 147
[2] Selective Hydrogenolysis of Glycerol to 1,2-Propanediol over Highly Active and Stable Cu/MgO Catalyst in the Vapor Phase
Pandhare, Nitin Naresh
Pudi, Satyanarayana Murty
Biswas, Prakash
Sinha, Shishir
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2016, 20 (06) : 1059 - 1067
[3] Cu:Al Nano Catalyst for Selective Hydrogenolysis of Glycerol to 1,2-Propanediol
Mane, Rasika B.
Hengne, Amol M.
Ghalwadkar, Ajay A.
Vijayanand, Subramanian
Mohite, Pravin H.
Potdar, Hari S.
Rode, Chandrashekhar V.
CATALYSIS LETTERS, 2010, 135 (1-2) : 141 - 147
[4] A Highly Active Cu–Pt/SiO2 Bimetal for the Hydrogenolysis of Glycerol to 1,2-Propanediol
Yumei Kang
Xiaosong Bu
Guangyu Wang
Xiaoqing Wang
Qianwen Li
Yisi Feng
Catalysis Letters, 2016, 146 : 1408 - 1414
[5] Advances in understanding the active sites of Cu catalysts in glycerol hydrogenolysis to 1,2-propanediol
Zhou, Wei
Ma, Xinbin
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2022, 66 (04): : 1288 - 1315
[6] Optimization of Hydrogenolysis of Glycerol to 1,2-Propanediol
Wolosiak-Hnat, Agnieszka
Milchert, Eugeniusz
Lewandowski, Grzegorz
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2013, 17 (04) : 701 - 713
[7] Copper carbide composite catalyst for hydrogenolysis of glycerol to 1,2-propanediol
Liu, Shan
Yu, Zhiquan
Lu, Chenyang
Wang, Yao
Sun, Fanfei
Sun, Zhichao
Liu, Yingya
Shi, Chuan
Wang, Anjie
FUEL, 2023, 334
[8] A Highly Active Cu-Pt/SiO2 Bimetal for the Hydrogenolysis of Glycerol to 1,2-Propanediol
Kang, Yumei
Bu, Xiaosong
Wang, Guangyu
Wang, Xiaoqing
Li, Qianwen
Feng, Yisi
CATALYSIS LETTERS, 2016, 146 (08) : 1408 - 1414
[9] Solvent effect on hydrogenolysis of glycerol to 1,2-propanediol over Cu-ZnO catalyst
Wang, Cancan
Jiang, Hong
Chen, Chang Lin
Chen, Rizhi
Xing, Weihong
CHEMICAL ENGINEERING JOURNAL, 2015, 264 : 344 - 350
[10] Insights into deactivation mechanism of Cu-ZnO catalyst in hydrogenolysis of glycerol to 1,2-propanediol
Du, Yan
Wang, Cancan
Jiang, Hong
Chen, Changlin
Chen, Rizhi
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2016, 35 : 262 - 267

← 1 2 3 4 5 →